Crystal Structure and Spectroscopic Behaviour of Oxoetoxo-bis(5,7-dichloro-8-hydroxyquinolinato)vanadium(V)Kristallstruktur und spektroskopisches Verhalten von Oxoetoxo-bis(5.7-dichlor-8-hydroxychinolinato)vanadium(V)

被引：0

作者：

Ana C. González-Baró

Oscar E. Piro

Beatriz S. Parajón-Costa

Enrique J. Baran

Eduardo E. Castellano

机构：

[1] Centro de Química Inorgánica (CEQUINOR),

[2] Facultad de Ciencias Exactas,undefined

[3] Universidad Nacional de La Plata,undefined

[4] 1900 La Plata,undefined

[5] Argentina,undefined

[6] Departmento de Física y Programa PROFIMO,undefined

[7] Facultad de Ciencias Exactas,undefined

[8] Universidad Nacional de La Plata,undefined

[9] 1900 La Plata,undefined

[10] Argentina.,undefined

[11] Instituto de Fisica de São Carlos,undefined

[12] Universidade de São Paulo 13560 São Carlos (SP),undefined

[13] Brazil,undefined

来源：

Monatshefte für Chemie / Chemical Monthly | 1998年 / 129卷 / 1期

关键词：

Keywords. Vanadium(V); Inorganic etoxoester; Crystal structure analysis; Vibrational spectra; Electronic spectra.;

D O I：

10.1007/PL00010102

中图分类号：

学科分类号：

摘要：

The title compound, a new example of an inorganic ester-like complex, was characterized by spectroscopic and X-ray crystallographic methods. It crystallizes in the triclinic space group P1 (a=9.413(2), b=10.595(3), c=11.783(2) Å, α=103.59(2), β=101.98(2), γ=99.40(2)°, Z=2). The structure was solved employing 2902 independent reflections with I>2σ(I) by direct and Fourier methods and refined by a full-matrix least-squares fit to R1=0.049. Infrared and Raman spectra of the solid compound and the electronic absorption spectra of its acetonitrilic and ethanolic solutions were recorded and are briefly discussed.

引用

页码：31 / 39

页数：8