Derivatives of syndiotactic cyclopropane-containing 1,2-polybutadiene

被引：0
|
作者：
A. B. Glazyrin
M. I. Abdullin
V. A. Dokichev
R. M. Sultanova
R. R. Muslukhov
E. R. Gazizova
机构：
[1] Bashkir State University,Institute of Organic Chemistry, Ufa Research Center
[2] Russian Academy of Sciences,undefined
来源：
Polymer Science Series B | 2014年 / 56卷
关键词：
Polymer Science Series; Cyclopropane; Diazomethane; Polybutadiene; Methoxycarbonyl;
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摘要：
The results of syndiotactic 1,2-polybutadiene cyclopropanation with diazomethane are demonstrated in an organic solvent in the presence of an organometallic catalyst to produce new polymers containing an unsubstituted cyclopropane group in the macrochain. A comparative evaluation of the levels of activity and regioselectivity of catalysts in 1,2-polybutadiene cyclopropanation is performed. This modification of syndiotactic 1,2-polybutadiene is shown to make it possible to obtain thermoplastic products with a relatively high energy saturation.
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页码：807 / 813
页数：6
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