Electrochemical reduction of mucochloric acid and its 5-alkoxy derivatives

被引：0
|
作者：
L. Z. Latypova
V. V. Yanilkin
A. R. Kurbangalieva
E. A. Berdnikov
G. A. Chmutova
机构：
[1] A. M. Butlerov Chemical Institute of the Kazan Federal University,A. E. Arbuzov Institute of Organic and Physical Chemistry
[2] Kazan Scientific Center of the Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 2012年 / 61卷
关键词：
mucochloric acid; 2(5; )-furanones; selectivity; electrochemical reduction; voltammetry; quantum chemical calculations;
D O I：
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中图分类号：
学科分类号：
摘要：
5-Alkoxy-3-chloro-2(5H)-furanones were synthesized by the electrochemical reduction of 5-alkoxy derivatives of mucochloric acid in acetonitrile on the lead electrode in the presence of acetic acid as a proton donor. A combined analysis of the experimental data and quantum chemical calculation of intermediates indicates the EEDC mechanism of reduction, including the tandem transfer of two electrons with chloride ion elimination at the stage of transfer of the second electron and protonation.
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页码：568 / 581
页数：13
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