Spectral and electroluminescent properties of coordination compounds of terbium (III) with ibuprofen (in solid form, chloroform solutions, and polyvinylcarbazole films)

被引:0
|
作者
L. G. Samsonova
T. N. Kopylova
K. M. Degtyarenko
N. V. Ponarin
S. B. Meshkova
I. I. Zheltvai
机构
[1] Tomsk State University,Bogatsky Physico
[2] National Academy of Sciences of Ukraine,Chemical Institute
来源
Optics and Spectroscopy | 2015年 / 119卷
关键词
Ibuprofen; Excitation Spectrum; Terbium; Chloroform Solution; Mixed Ligand Complex;
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摘要
Spectral properties of terbium (III) complexes with composition of TbL3DL, where L is an anion of d,l-2-(4-isobutylphenyl)propanoic acid (ibuprofen) and DL is 2,2′-dipyridyl (Dipy), 1,10-phenanthroline (Phen), or triphenylphosphine oxide (TPPO), have been studied in a solid form, chloroform solutions, and polyvinylcarbazole (PVC) films. It has been demonstrated that, in PVC films, occupation of the emitting level of terbium (III) involves the participation of polymer. The emission decay lifetimes of terbium in the chloroform solutions and PVC films have been measured. The possibility of the appearance of electroluminescence of complexes in PVC films has been studied.
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页码:221 / 228
页数:7
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