Special features of alkaline hydrolysis of 4-substituted buta-1,3-dienetriphenylphosphonium salts

被引：0

作者：

M. Zh. Ovakimyan

G. Ts. Gasparyan

A. S. Bichakhchyan

机构：

[1] National Academy of Sciences of Armenia,R&D Center of Organic and Pharmaceutical Chemistry

[2] Institute of Organic Chemistry,undefined

来源：

Russian Journal of General Chemistry | 2015年 / 85卷

关键词：

alkaline hydrolysis; anionotropic migration; phosphonium salt; diphenyl phosphoryl compound; triphenylphosphine oxide;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Alkaline hydrolysis of triphenylphosphonium salts containing 4-S-, N-, and O-substituted buta-1,3-diene group has been studied. 4-S-substituted phosphonium salts are hydrolyzed with formation of the corresponding diphenyl-1-phenyl-4-alkylsulfanylphosphoryl compounds, the products of anionotropic migration of the phenyl group. Under the same conditions, the 4-N- and O-substituted buta-1,3-diene phosphonium salts form triphenylphosphine oxide as the major product along minor diphenyl-4-N- or diphenyl-4-O-substituted buta-1,3-diene phosphine oxides.

引用

页码：1088 / 1092

页数：4

共 17 条

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Bichakhchyan, A. S.
RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (05) : 1088 - 1092
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