Parameters of Li2O2 · H2O crystallization from the LiOH-H2O2-H2O ternary system

被引:0
|
作者
Yu. A. Ferapontov
M. A. Ul’yanova
T. V. Sazhneva
机构
[1] OAO Roskhimzashchita Co.,
来源
关键词
LiOH; Lithium Hydroxide; Peroxide Compound; Solubility Method; Alkali Metal Hydroxide;
D O I
暂无
中图分类号
学科分类号
摘要
The decomposition kinetics of peroxide products contained in the liquid phase of the LiOH-H2O2-H2O ternary system were studied, and the applicability of the solubility method to studying this system was demonstrated for hydrogen peroxide concentrations in the liquid phase from 2 to 6 wt % and temperatures of 21–33°C. The stabilizing influence of solid Li2O2 · H2O on hydrogen peroxide decomposition was demonstrated. The temperature and concentration boundaries of existence were determined for the Li2O2 · H2O phase, whose identity was verified by chemical analysis and qualitative X-ray powder diffraction analysis.
引用
收藏
页码:1635 / 1640
页数:5
相关论文
共 50 条
  • [1] Parameters of Li2O2 • H2O Crystallization from the LiOH-H2O2-H2O Ternary System
    Ferapontov, Yu. A.
    Ul'yanova, M. A.
    Sazhneva, T. V.
    RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2008, 53 (10) : 1635 - 1640
  • [2] Kinetics of decomposition of the liquid phase of the ternary system LiOH-H2O2-H2O in the presence of the solid phase of Li2O2•H2O
    Ferapontov, Yu. A.
    Ul'yanova, M. A.
    Sazhneva, T. V.
    Kozlova, N. P.
    RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2008, 81 (01) : 26 - 29
  • [3] Kinetics of decomposition of the liquid phase of the ternary system LiOH-H2O2-H2O in the presence of the solid phase of Li2O2 · H2O
    Yu. A. Ferapontov
    M. A. Ul’yanova
    T. V. Sazhneva
    N. P. Kozlova
    Russian Journal of Applied Chemistry, 2008, 81 : 26 - 29
  • [4] THE EQUILIBRIUM 2LIOH(S) = LI2O(S) + H2O(G)
    GREGORY, NW
    MOHR, RH
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1955, 77 (08) : 2142 - 2144
  • [5] The water dimer reaction OH + (H2O)2 → (H2O)-OH + H2O
    Gao, Aifang
    Li, Guoliang
    Peng, Bin
    Xie, Yaoming
    Schaefer, Henry F., III
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2017, 19 (28) : 18279 - 18287
  • [6] SCF-CI STUDIES OF CORRELATION EFFECTS ON HYDROGEN-BONDING AND ION HYDRATION - SYSTEMS - H2O,H+ . H2O, LI+ . H2O, F- . H2O, AND H2O . H2O
    DIERCKSEN, GHF
    KRAEMER, WP
    ROOS, BO
    THEORETICA CHIMICA ACTA, 1975, 36 (04): : 249 - 274
  • [7] Structures and binding energies of O2-•H2O and O2•H2O
    Bell, AJ
    Wright, TG
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2004, 6 (18) : 4385 - 4390
  • [8] VAPOR PRESSURE OF LIOH.H2O + LI2SO4.H2O
    BACH, RO
    FORSYTH, MW
    BOARDMAN, WW
    CHIMIA, 1964, 18 (03) : 110 - &
  • [9] Deuterium exchange in the systems of H2O+/H2O and H3O+/H2O
    Anicich, V. G.
    Sen, A. D.
    International Journal of Mass Spectrometry and Ion Processes, 172 (1-2):
  • [10] THE SIMPLE CLUSTERS (H3O+)(H2O)1, (H3O+)(H2O)2, (H3O+)(H2O)3
    SCHAEFER, HF
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1985, 189 (APR-): : 103 - PHYS