Vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3 catalysts supported on TiO2-ZrO2 mixed oxide

被引：0

作者：

Dongsen Mao

Guanzhong Lu

Qingling Chen

机构：

[1] Shanghai Research Institute of Petrochemical Technology,Research Institute of Industrial Catalysis

[2] SINOPEC,undefined

[3] East China University of Science and Technology,undefined

来源：

Reaction Kinetics and Catalysis Letters | 2002年 / 75卷

关键词：

Beckmann rearrangement; cyclohexanone oxime; (-caprolactam; boria catalyst; titania-zirconia mixed oxide;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

A novel catalyst, boria supported on titania-zirconia mixed oxide, exhibits very high catalytic activity and selectivity in vapor-phase Beckmann rearrangement of cyclohexanone oxime to e-caprolactam. It gives 99.7% oxime conversion and 97.0% lactam selectivity at 300°C.

引用

页码：75 / 80

页数：5

共 50 条

[1] Vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3 catalysts supported on TiO2-ZrO2 mixed oxide
Mao, DS
Lu, GZ
Chen, QL
REACTION KINETICS AND CATALYSIS LETTERS, 2002, 75 (01): : 75 - 80
[2] Vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3/TiO2-ZrO2
Mao, DS
Chen, QL
Lu, GZ
APPLIED CATALYSIS A-GENERAL, 2003, 244 (02) : 273 - 282
[3] Effects of preparation conditions of TiO2-ZrO2 on vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3/TiO2-ZrO2 catalyst
Mao, Dong-Sen
Chen, Qing-Ling
Lu, Guan-Zhong
Shiyou Huagong/Petrochemical Technology, 2002, 31 (10):
[4] Deactivation and regeneration of B2O3/TiO2-ZrO2 catalyst for vapor-phase Beckmann rearrangement of cyclohexanone oxime
Mao, DS
Lu, GZ
Chen, QL
CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2003, 19 (04) : 381 - 386
[5] Effect of solvents on catalytic performance of B2O3/TiO2-ZrO2 for vapor-phase Beckmann rearrangement of cyclohexanone oxime
Mao, DS
Lu, GZ
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CHINESE JOURNAL OF CATALYSIS, 2005, 26 (04) : 271 - 276
[6] Study on vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3/TiO2-ZrO2 catalyst -: IV.: Effect of composition of TiO2-ZrO2
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Chen, QL
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CHINESE JOURNAL OF CATALYSIS, 2002, 23 (06) : 525 - 529
[7] Vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3/TiO2-ZrO2:: the effect of catalyst calcination temperature and solvent
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APPLIED CATALYSIS A-GENERAL, 2005, 279 (1-2) : 145 - 153
[8] Catalytic performance of B2O3/TiO2-ZrO2 for vapor-phase Beckmann rearrangement of cyclohexanone oxime:: the effect of boria loading
Mao, DS
Lu, GZ
Chen, QL
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CATALYSIS LETTERS, 2001, 77 (1-3) : 119 - 124
[9] Deactivation and regeneration of the B2O3/TiO2-ZrO2 catalyst in the vapor phase Beckmann rearrangement of cyclohexanone oxime
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JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2005, 240 (1-2) : 164 - 171
[10] Study on vapor-phase Beckmann rearrangement of cyclohexanone oxime over B2O3/TiO2-ZrO2 catalyst -: I.: Effect of B2O3 loading
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CHINESE JOURNAL OF CATALYSIS, 2002, 23 (01) : 9 - 14

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