Modeling of corrosion inhibition of copper-nickel alloy in hydrochloric acid by benzotriazole

被引:0
|
作者
A. A. Khadom
A. S. Yaro
机构
[1] University of Daiyla,Mechanical Engineering Department, College of Engineering
[2] University of Baghdad,Chemical Engineering Department, College of Engineering
关键词
activation parameters; corrosion inhibition; copper-nickel alloy; benzotriazole;
D O I
暂无
中图分类号
学科分类号
摘要
The corrosion inhibition of copper-nickel alloy by benzotriazole (BTA) in 1.5 M HCl has been investigated by weight loss and polarization techniques at different temperatures. Maximum value of inhibitor efficiency was 99.8% at 35°C and 0.1 M inhibitor concentration, while the lower value was 86.3% at 65°C and 0.02 M inhibitor concentration. The activation energy values were higher in presence of BTA which indicate that in presence of inhibitor, corrosion reaction requires more energy to occur. Two mathematical models were used to represent the weight loss corrosion rate data with high correlation coefficients. Electrochemical polarization measurements showed that BTA is a mixed type inhibitor.
引用
收藏
页码:2005 / 2012
页数:7
相关论文
共 50 条
  • [1] Modeling of corrosion inhibition of copper-nickel alloy in hydrochloric acid by benzotriazole
    Khadom, A. A.
    Yaro, A. S.
    [J]. RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2011, 85 (11) : 2005 - 2012
  • [2] ADSORPTION MECHANISM OF BENZOTRIAZOLE FOR CORROSION INHIBITION OF COPPER-NICKEL ALLOY IN HYDROCHLORIC ACID
    Khadom, Anees A.
    Yaro, Aprael S.
    Kadhum, Abdul Amir H.
    [J]. JOURNAL OF THE CHILEAN CHEMICAL SOCIETY, 2010, 55 (01): : 150 - 152
  • [3] Mass transfer effect on corrosion inhibition process of copper-nickel alloy in hydrochloric acid by Benzotriazole
    Khadom, Anees A.
    Yaro, Aprael S.
    [J]. JOURNAL OF SAUDI CHEMICAL SOCIETY, 2014, 18 (03) : 214 - 219
  • [4] Corrosion inhibition by naphthylamine and phenylenediamine for the corrosion of copper-nickel alloy in hydrochloric acid
    Khadom, Anees A.
    Yaro, Aprael S.
    Kadum, Abdul Amir H.
    [J]. JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS, 2010, 41 (01) : 122 - 125
  • [5] Corrosion Inhibition of Copper-nickel Alloy: Experimental and Theoretical Studies
    Khadom, Anees A.
    Yaro, Aprael S.
    Musa, Ahmed Y.
    Mohamad, Abu Bakar
    Kadhum, Abdul Amir H.
    [J]. JOURNAL OF THE KOREAN CHEMICAL SOCIETY-DAEHAN HWAHAK HOE JEE, 2012, 56 (04): : 406 - 415
  • [6] Dual function of benzotriazole as copper alloy corrosion inhibitor and hydrochloric acid flow improver
    Khadom A.A.
    [J]. Surface Engineering and Applied Electrochemistry, 2014, 50 (2) : 157 - 172
  • [7] The inhibition of copper-nickel alloy corrosion under controlled hydrodynamic condition in seawater
    Martinez, S.
    Metikos-Hukovic, M.
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2006, 36 (12) : 1311 - 1315
  • [8] INHIBITION OF CORROSION OF ALUMINUM-COPPER ALLOY IN HYDROCHLORIC-ACID
    PANDYA, JM
    [J]. BULLETIN OF ELECTROCHEMISTRY, 1995, 11 (09): : 409 - 411
  • [9] Corrosion of Copper in 0.1 M Hydrochloric Acid Solution with Benzotriazole as Corrosion Inhibitor
    M. Amini
    M. Toorani
    A. Sabour Rouhaghdam
    [J]. Protection of Metals and Physical Chemistry of Surfaces, 2020, 56 : 803 - 815
  • [10] Corrosion of Copper in 0.1 M Hydrochloric Acid Solution with Benzotriazole as Corrosion Inhibitor
    Amini, M.
    Toorani, M.
    Rouhaghdam, A. Sabour
    [J]. PROTECTION OF METALS AND PHYSICAL CHEMISTRY OF SURFACES, 2020, 56 (04) : 803 - 815