Lithium 1,5-bis[2-dioxyphosphinyl)phenoxy]-3-oxapentane hydrate: Synthesis, vibrational spectra, and crystal structure

被引：0

作者：

V. E. Baulin

M. A. Kiskin

I. S. Ivanova

E. N. Pyatova

D. V. Baulin

A. Yu. Tsivadze

机构：

[1] Russian Academy of Sciences,Frumkin Institute of Electrochemistry

[2] Russian Academy of Sciences,Institute of Physiologically Active Substances

[3] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

来源：

Russian Journal of Coordination Chemistry | 2011年 / 37卷

关键词：

Coordination Chemistry; Phosphoryl; Phenoxy; Coordinate Water Molecule; Phosphone Group;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The complex [Li(H3L2)(H2O)]n (I), where H4L2 is 1,5-bis[2-(dioxyphosphinyl)phenoxy]-3-oxapentane, is synthesized. Its crystal and molecular structures are determined by X-ray diffraction analysis and vibrational spectroscopy. Complex I is an isolated chain polymer in which the Li+ cations bind anions (H3L2)− of the bridging ligand. The crystals are orthorhombic: a = 8.1860(3) Å, b = 9.9093(4) Å, c = 23.6293(8) Å, V = 1916.75(12) Å3, Z = 4, space group Pna21. The framework of the polymer chain is stabilized by hydrogen bonds between two hydrogen atoms of the coordinated water molecule and two oxygen atoms of the ether and phosphone groups.

引用

页码：405 / 410

页数：5

共 50 条

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