Structure, synthesis, and voltammetric investigation of 1-(quinolin-2-yl)-2-(pyran-2-yl)ethane-1,2-dione derivatives

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作者
V. V. Tkachev
G. V. Shilov
S. M. Aldoshin
E. A. Gusakov
Yu. A. Sayapin
A. A. Bumber
V. N. Komissarov
V. I. Minkin
机构
[1] Russian Academy of Sciences,Institute of Problems of Chemical Physics
[2] Institute of Physical and Organic Chemistry at the Southern Federal University,Southern Scientific Center
[3] Russian Academy of Sciences,undefined
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关键词
Dione Derivative; Tetrabutylammonium Perchlorate; Compound IIIc; Intramolecular Ring; Quinoline Fragment;
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摘要
By the XRD analysis the structure was established of 1-(7,8-dimethyl-4-chloroquinolin-2-yl)-2-[3,5-di(tert-butyl)-6-oxo-6H-pyran-2-yl]ethane-1,2-dione formed as a result of the oxidation of 3,5-di(tert-butyl)-6-[(Z)-2-(quinolin-2-yl)-1-hydroxyethen-1-yl]pyran-2-ones. By the cyclic voltammetry the oxidation of 1-(quinolin-2-yl)-2-(pyran-2-yl)ethane-1,2-dione derivatives was shown to proceed in two stages.
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页码:151 / 157
页数:6
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