Synthesis of New Cyclophane Host Molecules and Crystal Structures of Their Compounds with Hydrocarbon Guests

被引:0
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作者
N. Kent Dalley
Xiaolan Kou
Richard A. Bartsch
Piotr Kus
机构
[1] Brigham Young University,Department of Chemistry and Biochemistry
[2] Texas Tech University Lubbock,Department of Chemistry and Biochemistry
关键词
aromatic hydrocarbon guest; CH–π interactions; cyclophane host; solid-state structure;
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摘要
Three new cyclophane host molecules 2, 4, and 6 are prepared by connecting the oxygen atoms of twoα ,α'–di(4-hydroxyphenyl)-1,4-diisopropylbenzene units with two di-, tetra-, and hexamethylene spacers, respectively. Solid-state structures are determined for host 2 with a hexane guest, host 4 with a toluene guest and a solvating toluene molecule, host 4 with a p-xylene guest,and host 6 with two p-xylene guests.
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页码:139 / 148
页数:9
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