Benzaldehyde N,N-Dimethylhydrazone in the Reaction with 4-Oxo-2-pentafluorophenoxy-5,6-benzo- 1,3,2-dioxaphosphorinane. Preparation and Spatial Structure of 4-Dimethylamino-2,5-dioxo-2-pentafluorophenoxy-3-phenyldihydro-6,7-benzo-1,4,2-oxazaphosphepine

被引：0
|
作者：
V. F. Mironov
A. T. Gubaidullin
G. A. Ivkova
I. A. Litvinov
B. I. Buzykin
L. M. Burnaeva
I. V. Konovalova
机构：
[1] Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
[2] Kazan,undefined
来源：
Russian Journal of General Chemistry | 2001年 / 71卷
关键词：
Hydrolysis; Phosphorus; Spatial Structure; Benzaldehyde; Diffraction Study;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Benzaldehyde N,N-dimethylhydrazone with 4-oxo-2-pentafluorophenoxy-5,6-benzo-1,3,2-dioxaphosphorinane is capable to yield with high stereoselectivity a product of the phosphorus heterocycle expansion: unstable to hydrolysis 4-dimethylamino-2,5-dioxo-2-pentafluorophenoxy-3-phenyldihydro-6,7-benzo-1,4,2-oxazaphosphepine. The configuration of the prevailing isomer of the latter was determined by X-ray diffraction study.
引用
收藏
页码：420 / 428
页数：8
相关论文
共 20 条
  • [1] Benzaldehyde N,N-dimethylhydrazone in the reaction with 4-oxo-2-pentafluorophenoxy-5,6-benzo-1,3,2-dioxaphosphorinane.: Preparation and spatial structure of 4-dimethylamino-2,5-dioxo-2-pentafluorophenoxy-3-phenyldihydro-6,7-benzo-1,4,2-oxazaphosphepine
    Mironov, VF
    Gubaidullin, AT
    Ivkova, GA
    Litvinov, IA
    Buzykin, BI
    Burnaeva, LM
    Konovalova, IV
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2001, 71 (03) : 420 - 428
  • [2] Reactions of 2-Alkoxy-4-oxo-5,6-benzo- 1,3,2-dioxaphosphorinanes with Imines. Synthesis and Steric Structure of 6,7-Benzo-1,4,2-oxazaphosphepine Derivatives
    V. F. Mironov
    A. T. Gubaidullin
    L. M. Burnaeva
    I. A. Litvinov
    G. A. Ivkova
    S. V. Romanov
    T. A. Zyablikova
    A. I. Konovalov
    I. V. Konovalova
    Russian Journal of General Chemistry, 2004, 74 : 32 - 47
  • [3] Reactions of 2-alkoxy-4-oxo-5,6-benzo-1,3,2-dioxaphosphorinanes with imines. Synthesis and steric structure of 6,7-benzo-1,4,2-oxazaphosphepine derivatives
    Mironov, VF
    Gubaidullin, AT
    Burnaeva, LM
    Litvinov, IA
    Ivkova, GA
    Romanov, SV
    Zyablikova, TA
    Konovalov, AI
    Konovalova, IV
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2004, 74 (01) : 32 - 47
  • [4] Synthesis and spatial structure of 2-pentafluorophenoxy-4-oxo-5,6-benzo-1,3,2-dioxaphosphorinane with α-diimines.: Preparation of λ4-1,3,2-diazaphospholenes
    Mironov, VF
    Ivkova, GA
    Burnaeva, LM
    Gryaznova, TV
    Konovalova, IV
    Gryaznov, PI
    Kibardin, AM
    Musin, RZ
    Pudovik, AN
    ZHURNAL OBSHCHEI KHIMII, 1998, 68 (04): : 592 - 596
  • [5] REACTION OF 2-ALKOXY-4-OXO-5,6-BENZO-1,3,2-DIOXAPHOSPHORINANES WITH N-METHYLBENZALIMINE - 6,7-BENZO-1,4,2-OXAZAPHOSPHEPANES
    MIRONOV, VF
    KONOVALOVA, IV
    BURNAEVA, LM
    KHLOPUSHINA, GA
    SHASTINA, YS
    ZHURNAL OBSHCHEI KHIMII, 1994, 64 (07): : 1217 - 1218
  • [6] Reaction of 2-R-4-hydroxo-5,6-benzo-1,3,2-dioxaphosphorinanes with chloral and bromal. X-ray diffraction analysis of 2,5-dioxo-2-phenyl-3-trichloromethyl-6,7-benzo-1,4,2-dioxaphosphepines and 2,5-dioxo-2-methoxy-3-trichloromethyl-6,7-benzo-1,4,2-dioxaphosphepines
    Mironov, VF
    Litvinov, IA
    Gubaidullin, AT
    Aminova, RM
    Burnaeva, LM
    Azancheev, NM
    Filatov, ME
    Konovalova, IV
    ZHURNAL OBSHCHEI KHIMII, 1998, 68 (07): : 1080 - 1095
  • [7] Synthesis and steric structure of the derivatives of 2-R-5-oxo-3,3-bis(trifluoromethyl)-6,7-benzo-1,4,2-and 2-R-5-oxo-4,4-bis(trifluoromethyl)-6,7-benzo-1,3,2-oxazaphosphepine 2-oxides
    Litvinov, IA
    Mironov, VF
    Gubaidullin, AT
    Konovalova, IV
    Burnaeva, LM
    Konovalov, AI
    Ivkova, GA
    Kurykin, MA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 1999, 69 (05) : 744 - 766
  • [8] Reaction of 2-R-4-oxo-5,6-benzo-1,3,2-dioxaphosphorinanes with Methyl 2-oxo-3,3,3-trifluoropropionate. Steric Structure of 5-oxo-4-methoxycarbonyl-4-trifluoromethyl-2-ethoxy-6,7-benzo-1,4,2-dioxaphosphepine 2-oxide
    Mironov, VF
    Gubaidullin, AT
    Konovalova, IV
    Litvinov, IA
    Burnaeva, LM
    Zyablikova, TA
    Romanov, SV
    Mavleev, RA
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2000, 70 (11) : 1706 - 1726
  • [9] Synthesis and spatial structure of 2-(2,2,3,3-tetrafluoropropoxy)-2,5-dioxo-3-methyl-3-trifluoromethyl-6,7-benzo-1,4,2-dioxaphosphepine
    Mironov, VF
    Gubaidullin, AT
    Litvinov, IA
    Burnaeva, LM
    Zyablikova, TA
    Khlopushina, GA
    Konovalova, IV
    ZHURNAL OBSHCHEI KHIMII, 1998, 68 (04): : 597 - 602
  • [10] Synthesis and crystal structure of 2-R-2,5-dioxo-5,6-benzo-1,4,2-and-1,3,2-dioxaphosphepines
    Burnaeva, LM
    Mironov, VF
    Konovalova, IV
    Goruynov, EI
    Mastruykova, TA
    Gabaidullin, AT
    Litvinov, IA
    Yashagina, OV
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2002, 177 (8-9) : 2137 - 2137
12