Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole: Synthesis and study

被引：0
|
作者：
M. B. Bushuev
A. V. Virovets
D. Yu. Naumov
Yu. G. Shvedenkov
L. A. Sheludyakova
V. N. Elokhina
E. G. Boguslavsky
L. G. Lavrenova
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
[2] Russian Academy of Sciences,Irkutsk Institute of Chemistry, Siberian Division
来源：
Russian Journal of Coordination Chemistry | 2006年 / 32卷
关键词：
Physical Chemistry; Inorganic Chemistry; Triazole; Exchange Interaction; Antiferromagnetic Exchange;
D O I：
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摘要：
The Cu(II) and Co(II) complexes with 3,5-diphenyl-4-amino-1,2,4-triazole (L) of the composition CuLA2 · H2O (A = Cl−, Br−), CuL2A2 (A = Cl−, Br−, NO3−), CoL2A2 · nH2O (A = Cl−, n = 1; A = NCS−, n = 0) are synthesized. In these complexes, the ligand L is coordinated to a metal in monodentate mode through the heterocyclic N(1) atom. The Cu: L = 1: 1 complexes have binuclear structures with the anions acting as bridges, whereas the M: L = 1: 2 complexes are mononuclear. Both ferro-and antiferromagnetic exchange interactions are detected for the synthesized complexes.
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页码：309 / 320
页数：11
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