Reaction of cyclopentadienyllutetium anthracenide with azobenzene. Synthesis and molecular and crystal structure of the binuclear complex [C5H5(THF)Lu(μ−η2:η2−PhN—NPh)]2(THF)2 and its dynamic behavior in solution

被引：0
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作者：
D. M. Roitershtein
K. A. Lyssenko
P. A. Belyakov
M. Yu. Antipin
E. S. Petrov
机构：
[1] L. Ya. Karpov Scientific-Research Physicochemical Institute,State Scientific Center of the Russian Federation
[2] A. N. Nesmeyanov Institute of Organoelement Compounds,Higher Chemical College
[3] Russian Academy of Sciences,undefined
[4] Russian Academy of Sciences,undefined
来源：
Russian Chemical Bulletin | 1997年 / 46卷
关键词：
organolanthanide compounds; lutetium; azobenzene; complex; molecular and crystal structure;
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摘要：
The reaction of the cyclopentadienyllutetium anthracenide, C5H5Lu(C14H10)2−(THF)2 (1), with azobenzene yielded the [C5H5(THF)Lu(μ−η2:η2−PhN—NPh)]2(THF)2 (2) binuclear complex. The structure of the reaction product was established by X-ray structural analysis. The dynamic behavior of complex2 in a THF-d8 solution was studied by1H NMR spectroscopy in the temperature range of 265–330 K.
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页码：1590 / 1594
页数：4
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