Preparation of powdered activated carbon from rice husk and its methane adsorption properties

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作者
Marriyappan Sivagnanam Balathanigaimani
Hyun-Chul Kang
Wang-Geun Shim
Chan Kim
Jae-Wook Lee
Hee Moon
机构
[1] Chonnam National University,Faculty of Applied Chemical Engineering
[2] Seonam University,Department of Environmental and Chemical Engineering
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关键词
Adsorbed Natural Gas; Activated Carbon; High Pressure Adsorption; Isosteric Heat of Adsorption;
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摘要
Success of adsorbed natural gas (ANG) storage process is mainly based on the characteristics of the adsorbent, so various synthesized adsorbents were analyzed for methane adsorption on a thermodynamic basis. Activated carbon from rice husk (AC-RH) was synthesized and its methane adsorption capacities were compared with phenol based activated carbons (AC-PH2O and AC-PKOH). The adsorption experiments were conducted by volumetric method under various constant temperatures (293.15, 303.15, 313.15 and 323.15 K) and pressure up to 3.5MPa. Maximum methane adsorption was observed in AC-RH as its surface area is higher than the other two adsorbents. The experimental data were correlated well with Langmuir-Fruendlich isotherms. In addition, isosteric heat of adsorption was calculated by using Clausius-Clapeyron equation.
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页码:663 / 668
页数:5
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