Mixed-Ligand Coordination Compounds CdL{(i-C4H9)2PS2}2(L = Phen, 2,2"-Bipy, and 4,4"-Bipy): Synthesis, Structure, and Thermal Properties. Polymeric Structure of [Cd(4,4"-Bipy){(i-C4H9)2PS2}2]n

被引：0
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作者：
S. V. Larionov
V. G. Shchukin
L. A. Glinskaya
R. F. Klevtsova
A. P. Mazhara
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Division
来源：
Russian Journal of Coordination Chemistry | 2001年 / 27卷
关键词：
Precipitation; Polymeric Chain; Thermal Property; Phen; Diffraction Data;
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学科分类号：
摘要：
Volatile mixed-ligand compounds of Cd(i-Bu2PS2)2with Phen, 2,2"-Bipy, and 4,4"-Bipy were synthesized. Their single crystals were grown. X-ray diffraction data (a CAD4 diffractometer, MoKαradiation, 2140 Fhkl, R=0.0251) were used to determine the structure of [Cd(4,4"-Bipy)(i-Bu2PS2)2]. The crystals are mono-clinic: a= 14.678(3) Å, b= 11.866(2) Å, c= 19.655(4) Å, β = 102.17(3)°, V= 3346(1) Å3, Z= 4, ρcalcd= 1.364 g/cm3, space group C2/c. The structure is built from linear polymeric chains arranged along the [010] direction. The coordination polyhedron of the Cd atom is a distorted octahedron (4S + 2N). The thermal properties of these compounds, studied both in air and in vacuo, allow one to use them for preparing CdS films by chemical precipitation from the gas phase.
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页码：463 / 468
页数：5
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