A topological pattern for the understanding of the stability and aromaticity of closo-boranes: constructing closo-borane from nido-boranes

被引：0

作者：

Rongbao Liao

Zhimei Tian

Yumin Cui

Rongjian Sa

机构：

[1] Fuyang Teachers College,Department of Chemistry

[2] Chinese Academy of Sciences,Fujian Institution of Research on Science of Matter

来源：

Structural Chemistry | 2012年 / 23卷

关键词：

Borane; Stability; Aromaticity; Topological; B; H; B; H;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The closo-boranes BnHn2− (6 ≤ n ≤ 12) have been constructed topologically by fusing together of the two component nido-boranes B5H9 and B6H10. The stability and aromaticity of the closo-boranes can be regarded as inherited from the two component nido-boranes, and the closo-boranes which can be formed by two same nido-boranes through sharing a “ring” fragment or without sharing any BH fragment are more stable than other types of closo-boranes. It can be anticipated that the constructing method of this article can bring enlightment to the structural interpretation process of other systems.

引用

页码：1797 / 1800

页数：3

共 9 条

[1] A topological pattern for the understanding of the stability and aromaticity of closo-boranes: constructing closo-borane from nido-boranes
Liao, Rongbao
Tian, Zhimei
Cui, Yumin
Sa, Rongjian
STRUCTURAL CHEMISTRY, 2012, 23 (06) : 1797 - 1800
[2] Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
Golub, Igor E.
Filippov, Oleg A.
Kulikova, Vasilisa A.
Belkova, Natalia V.
Epstein, Lina M.
Shubina, Elena S.
MOLECULES, 2020, 25 (12):
[3] Relative Stability of closo-closo, closo-nido, and nido-nido Macropolyhedral Boranes: The Role of Orbital Compatibility
Shameema, Oottikkal
Jemmis, Eluvathingal D.
CHEMISTRY-AN ASIAN JOURNAL, 2009, 4 (08) : 1346 - 1353
[4] IS CLOSO, NIDO, OR ARACHNO CLASSIFICATION FOR BORANES A FUNCTION OF TOPOLOGICAL DESCRIPTION OF MOLECULE
RUDOLPH, RW
INORGANIC CHEMISTRY, 1978, 17 (04) : 1097 - 1098
[5] A topological pattern for understanding the structures of boranes and borane analog compounds
Liao, Rongbao
Zhu, Yun
Li, Qiaohong
Sa, Rongjian
STRUCTURAL CHEMISTRY, 2015, 26 (01) : 353 - 364
[6] A topological pattern for understanding the structures of boranes and borane analog compounds
Rongbao Liao
Yun Zhu
Qiaohong Li
Rongjian Sa
Structural Chemistry, 2015, 26 : 353 - 364
[7] Four decades of organic chemistry of closo-boranes:: A synthetic toolbox for constructing liquid crystal materials.: A review
Kaszynski, P
COLLECTION OF CZECHOSLOVAK CHEMICAL COMMUNICATIONS, 1999, 64 (06) : 895 - 926
[8] Theoretical study of the structure and stability of cage-substituted icosahedral closo-boranes, alanes, and gallanes MiM′12 − iH122− (M, M′ = B, Al, and Ga; i = 0–12)
O. P. Charkin
Russian Journal of Inorganic Chemistry, 2011, 56 : 1775 - 1781
[9] Theoretical study of the structure and stability of cage-substituted icosahedral closo-boranes, alanes, and gallanes M i M'12-i H 12 2- (M, M' = B, Al, and Ga; i=0-12)
Charkin, O. P.
RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2011, 56 (11) : 1775 - 1781

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