Reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid and synthesis of ammine(nitrato)nitrosoruthenium complexes

被引：0
|
作者：
E. V. Kabin
V. A. Emel’yanov
V. A. Vorob’yev
N. I. Alferova
S. V. Tkachev
I. A. Baidina
机构：
[1] Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry, Siberian Branch
[2] Novosibirsk State University,undefined
来源：
Russian Journal of Inorganic Chemistry | 2012年 / 57卷
关键词：
Ruthenium; Coord; Mother Liquor; Nitric Acid Solution; Concentrate Nitric Acid;
D O I：
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学科分类号：
摘要：
The reaction of trans-[RuNO(NH3)4(OH)]Cl2 with nitric acid has been studied. Reaction products have been identified by IR spectroscopy, NMR, mass spectrometry, powder and single-crystal X-ray diffraction, and chemical analysis. Synthesis methods have been developed for amminenitrosoruthenium complexes containing outer-sphere and coordinated nitrate ions: trans-[RuNO(NH3)4(H2O)](NO3)3 (I), trans-[RuNO(NH3)4(NO3)](NO3)2 (II), and fac-[RuNO(NH3)2(NO3)3] (III). Complex II has two polymorphs: monoclinic and tetragonal. The latter has been studied by X-ray crystallography.
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页码：1146 / 1153
页数：7
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