Valence state of hydrogen in hydrides of intermetallic compounds

被引：0
|
作者：
K. N. Semenenko
V. V. Burnasheva
N. A. Yakovleva
E. A. Ganich
机构：
[1] M. V. Lomonosov Moscow State University,Department of Chemistry
来源：
Russian Chemical Bulletin | 1998年 / 47卷
关键词：
intermetallic compound; mechanism of hydride dispersion; redox process; hydride ion;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The experimental data on the mechanism of hydride dispersion of intermetallic compounds of the LaNi5 type and the crystal structures of hydride phases based on these compounds were analyzed. A new approach was suggested and substantiated, which allows one to consider hydride dispersion as a result of a redox process associated with the formation of Hδ− hydride ions at concentrations of hydrogen in the solid hydrideCH>-CHcr. The value ofCHcr is determined by the redox potential of the reaction Hδ++Mδ−⇌Hδ′−+Mδ′+.
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页码：209 / 212
页数：3
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