Comparison of sodium zirconium phosphate and calcium zirconium phosphate structures for the retention of fluoride

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作者
Ambarish Dey
Amit Das Gupta
Debrata Basu
Ritu D. Ambashta
P. K. Wattal
Sanjiv Kumar
Monique Body
P. R. Rajamohanan
机构
[1] Central Glass and Ceramic Research Institute,Bio
[2] BARC Trombay,Ceramics and Coating Division
[3] NCCCM/BARC,Process Development Division
[4] Université du Maine,LUNAM Université, Institut des Molécules et Matériaux du Mans, CNRS UMR 6283
[5] National Chemical Laboratory,undefined
关键词
NZP; Microwave; Fluoride characterization; PIGE; F-NMR;
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摘要
Fluoride anion interaction has been explored for the first time to investigate how the structure of sodium zirconium phosphate (NZP) and calcium zirconium phosphate (CZP) can be altered in its presence. Different compositions were made by adding NaF and CaF2 in CZP and NZP matrices respectively. Fluoride interaction differs with NZP and CZP structure as suggested by F-NMR data. The addition of fluoride to the NZP or CZP structure enables to stabilize the structure at a low temperature of 600–700 °C under microwave conditions.
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页码:19 / 24
页数:5
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