Chemistry of oxomolybdenum(V) and (VI) complexes incorporating oxygen, nitrogen and/or sulfur donor atoms. Part 1. Synthesis and characterization of [Mo2O3L4] (LH = HSCH2CH2CO2H, HSCH2CO2Me or HSCH2CH2CO2Me) and [MoO2L′2] (L′H = HOC6H4NH2, HOCH2C6H4NH2, HOC6H4CHO or HOC10H8N)

被引：0

作者：

Purnima Nag

Rakesh Bohra

Ram C. Mehrotra

Raju Ratnani

机构：

[1] University of Rajasthan,Department of Chemistry

[2] MDS University,Department of Applied Chemistry

来源：

Transition Metal Chemistry | 2002年 / 27卷

关键词：

Colour; Alcohol; 2H2O; Propanate; Donor Atom;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Reactions of an acidified aqueous solution of Na2MoO4 · 2H2O with 3-mercaptopropionic acid, 2-mercaptomethylethanoate and 3-mercaptomethyl propanate yield blue oxo-bridged MoV complexes of the type [Mo2O3L4], whereas corresponding reactions with 2-aminophenol, 2-aminobenzyl alcohol, salicylaldehyde and 2-methyl-8-hydroxyquinoline, yield yellow dioxomolybdenum(VI) complexes, [MoO2L′2]. All these coloured solids are sparingly soluble, even in coordinating solvents. They have been characterized by elemental and spectroscopic analysis.

引用

页码：321 / 325

页数：4

共 50 条

[1] Chemistry of oxomolybdenum(V) and (VI) complexes incorporating oxygen, nitrogen and/or sulfur donor atoms.: Part 1.: Synthesis and characterization of [Mo2O3L4] (LH = HSCH2CH2CO2H, HSCH2CO2Me or HSCH2CH2CO2Me) and [MoO2L′2] (L′H = HOC6H4NH2, HOCH2C6H4NH2, HOC6H4CHO or HOC10H8N)
Nag, P
Bohra, R
Mehrotra, RC
Ratnani, R
TRANSITION METAL CHEMISTRY, 2002, 27 (03) : 321 - 325
[2] p-Nitrophenylacetic acid - O2C6H4CN+H2SO4+2H(2)O -> (p)NO2C6H4CH2CO2H+NH4HSO4
Robertson, GR
Adams, R
Calvery, HO
ORGANIC SYNTHESES, 1922, 2 : 59 - 60
[3] Synthesis, characterization and reactions of cluster complexes Fe-4(HSCH2CH2SH)(2)(CO)(12), Fe-2(HSCH2CH2SH)(CO)(8) and Fe-2(HSCH2CH2SH)(CO)(6)
Ullah, SS
Alam, FR
Ishizuka, Y
Goto, M
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1996, 35 (11): : 930 - 934
[4] Synthesis, structure and characterization of (NH4)2[Cu2(H2O)4(NH3CH2COO)2(NH2CH2COO)2]H2V10O28•6H2O
Klistincova, Lenka
Rakovsky, Erik
Schwendt, Peter
Plesch, Gustav
Gyepes, R.
INORGANIC CHEMISTRY COMMUNICATIONS, 2010, 13 (11) : 1275 - 1277
[5] H3PO4－i－C3H7OAl－H2NCH2CH2NH2－HOC
高秋明，李守贵，徐如人
高等学校化学学报, 1995, (03) : 338 - 341
[6] A Family of New Glutarate Compounds: Synthesis, Crystal Structures of: Co(H2O)5L(1), Na2[CoL2] (2), Na2[L(H2L)4/2] (3), {[Co3(H2O)6L2](HL)2} • 4H2O (4), {[Co3(H2O)6L2](HL)2} • 10H2O (5), {[Co3(H2O)6L2]L2/2} • 4H2O (6), and Na2{[Co3(H2O)2]L8/2] • 6H2O (7), and Magnetic Properties of 1 and 2 with H2L = HOOC-(CH2)3-COOH
Zheng, Yue-Qing
Lin, Jian-Li
Xu, Wei
Xie, Hong-Zhen
Sun, Jie
Wang, Xian-Wen
INORGANIC CHEMISTRY, 2008, 47 (22) : 10280 - 10287
[7] Synthesis and crystal structure of cluster [C6H4-1,2(CO2CH2C2H-μ)2][Co2(CO)6]2
Chen, XN
Zhang, J
Yin, YQ
Sun, J
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 1999, 18 (04) : 249 - 253
[8] Synthesis and Characterization of Co(II) Complexes of N-Thiophosphorylated Thioureas RC(S)NHP(S)(OiPr)2 (R = Me2N, 2-MeC6H4NH, 2,6-Me2C6H3NH,2,4,6-Me3C6H2NH)
Babashkina, Maria G.
Safin, Damir A.
Bolte, Michael
Klein, Axel
ACTA CHIMICA SLOVENICA, 2010, 57 (02) : 475 - 479
[9] PREPARATION AND CHARACTERIZATION OF (C6H5CH2CH2NH3)2SNI4 AND (C6H5CH2CH2NH3)2SNBR4
PAPAVASSILIOU, GC
KOUTSELAS, JB
LAGOUVARDOS, DJ
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1993, 48 (07): : 1013 - 1014
[10] Preparation and crystal structures of the silver(I) carboxylates [Ag2{C6H4-(CO2)2}(NH3)$ -2$/], [NH4][Ag5{C6H3(CO2)3} 2(NH3$ /)$-2(H2O)2] QQ H2O and [NH4]-[Ag{C4H2N2(CO2)2 }]
Smith, G.
Reddy, A. N.
Byriel, K. A.
Kennard, C. H. L.
Journal of the Chemical Society.Dalton Transactions, 1996,

← 1 2 3 4 5 →