Thermodynamic characteristics of neodymium and terbium pyrazolonate complexes

被引：0
|
作者：
N. M. Lazarev
Yu. A. Bessonova
B. I. Petrov
G. A. Abakumov
L. N. Bochkarev
A. V. Safronova
A. V. Arapova
A. V. Krasnov
G. V. Girichev
机构：
[1] Russian Academy of Sciences,Razuvaev Institute of Organometallic Chemistry
[2] Lobachevsky State University of Nizhni Novgorod,undefined
[3] Ivanovo State University of Chemistry and Technology,undefined
来源：
Russian Journal of Coordination Chemistry | 2014年 / 40卷
关键词：
Neodymium; Coordination Chemistry; Saturated Vapor; Terbium; Thermodynamic Characteristic;
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中图分类号：
学科分类号：
摘要：
The sublimation of 1-phenyl-3-methyl-4-isobutyryl-5-pyrazolonate complexes of neodymium and terbium was studied by the Knudsen effusion method with mass spectrometric gas phase monitoring. The gas phase was shown to contain only monomeric molecular species. The sublimation enthalpy (kJ/mol) for Nd complex is 205.9 ± 2.7 and that for the Tb complex is 208.0 ± 4.0.
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页码：179 / 183
页数：4
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