We generalize the definition of a pattern from permutations to alternating sign matrices. The number of alternating sign matrices avoiding 132 is proved to be counted by the large Schröder numbers, 1, 2, 6, 22, 90, 394, .... We give a bijection between 132-avoiding alternating sign matrices and Schröder paths, which gives a refined enumeration. We also show that the 132-, 123-avoiding alternating sign matrices are counted by every second Fibonacci number.