Synthesis and structure of lower rim-substituted alkynyl derivatives of thiacalix[4]arene

被引：0
|
作者：
A. A. Murav’ev
F. B. Galieva
A. G. Strel’nik
R. I. Nugmanov
M. Grüner
S. E. Solov’eva
Sh. K. Latypov
I. S. Antipin
A. I. Konovalov
机构：
[1] Russian Academy of Sciences,Arbuzov Institute of Organic and Physical Chemistry, Kazan Scientific Center
[2] Ulyanov-Lenin Kazan (Volga Region) Federal University,Butlerov Institute of Chemistry
[3] Dresden University of Technology,undefined
来源：
Russian Journal of Organic Chemistry | 2015年 / 51卷
关键词：
EtOAc; Macrocycle; Propargyl; HMBC Correlation; Partial Cone;
D O I：
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中图分类号：
学科分类号：
摘要：
Lower-rim substituted bis- and tetrakis(alkynyloxy)thiacalix[4]arenes in cone and 1,3-alternate configurations were synthesized by the Mitsunobu reaction, and their structure was determined using homoand heteronuclear one- and two-dimensional NMR techniques. Bis(prop-2-yn-1-yloxy)thiacalix[4]arene was found to exist in conformational equilibrium whose position depends on the temperature and reaction conditions.
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页码：1334 / 1342
页数：8
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