Specific interactions in metal salts and complexes with cluster boron anions BnHn2− (n = 6, 10, 12)

被引：0
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作者：
E. A. Malinina
V. V. Avdeeva
L. V. Goeva
I. N. Polyakova
N. T. Kuznetsov
机构：
[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry
来源：
Russian Journal of Inorganic Chemistry | 2011年 / 56卷
关键词：
Boron; Specific Interaction; Aminoguanidine; Cluster Anion; Secondary Interaction;
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摘要：
Specific interactions that appear in metal salts and complexes with cluster boron anions BnHn2− (n = 6, 10, 12) have been discussed. These interactions, as well as chemical bonds, involve vertices, edges, or faces of boron polyhedra. Specific interactions have a considerable effect on the structure of compounds, making a significant contribution to the formation of the unit cell and forming supramolecular assemblies. Compounds containing BnHn2− cluster anions shed new light onto the nature of specific interactions owing to their many-center character and great variety.
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