Copper(II)–8-mercaptoquinoline, copper(II)–5,8-dimercaptoquinoline and copper(II)–5-thiomethyl-8-mercaptoquinoline complexing in a copper(II)hexacyanoferrate(II) gelatin-immobilized matrix

被引：0

作者：

Oleg V. Mikhailov

Tatyana B. Tatarintseva

Tatyana S. Gorbunova

Vladimir F. Sopin

机构：

[1] Kazan State Technological University,

来源：

Transition Metal Chemistry | 2000年 / 25卷

关键词：

Copper; Physical Chemistry; Aqueous Solution; Inorganic Chemistry; Coordination Compound;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

Novel complexing processes in the CuII–8-mercaptoquinoline, CuII–5,8-dimercaptoquinoline and CuII–5-thiomethyl-8-mercaptoquinoline systems proceeding in the copper(II)hexacyanoferrate(II) gelatin-immobilized matrix in contact with aqueous solutions of the ligands indicated, have been studied. Under the conditions specified for complexing in the CuII–8-mercaptoquinoline system, only a monomeric water-insoluble coordination compound was formed. In the CuII–5,8-dimercaptoquinoline system, three coordination compounds were formed and, in the CuII–5-thiomethyl-8-mercaptoquinoline system, two such compounds were formed. Conversely, complexing in solution or solid phase results in the formation only coordination compounds in each of the system studied.

引用

页码：45 / 51

页数：6

共 50 条

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