The oxidation of sulfide to sulfoxide on Ti-complex/MCM-41 catalyst

被引:0
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作者
Ilyes Khedher
Abdelhamid Ghorbel
机构
[1] Laboratoire de Chimie des Matériaux et Catalyse,Département de Chimie, Faculté des Sciences de Tunis
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关键词
Asymmetric oxidation; Sulfide; Sulfoxide; MCM-41; Catalysis; Synthesis;
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摘要
The heterogeneous Kagan-type catalyst was prepared by an in situ method using MCM-41 as support. The influence of the incorporation process on the structure of MCM-41 was studied using XRD, FT-IR, UV-vis, 29Si-MAS-NMR and N2 adsorption–desorption. The obtained materials showed a definite catalytic activity on the oxidation of sulfide to sulfoxide in the medium containing dichloromethane (solvent) and H2O2 or TBHP (oxidant).
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页码:501 / 507
页数:6
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