Water radiolysis in the presence of uranyl silicate

被引：0
|
作者：
A. A. Garibov
T. N. Agaev
M. N. Mirzoev
S. M. Aliev
机构：
[1] National Academy of Sciences of Azerbaijan,Institute of Radiation Problems
来源：
Russian Journal of Physical Chemistry A | 2015年 / 89卷
关键词：
uranyl silicates; water radiolysis; radiation catalytic activity;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Uranyl silicates with different uranyl contents were synthesized. For comparison, the radiation catalytic activity of uranyl silicate with 10% uranium and starting silicate during the radiolytic decomposition of water was studied. The heterogeneous radiolysis of water was investigated in the adsorbed and liquid states in contact with uranyl silicate and silicate samples. The effect of the uranyl cations, the state of water, and reaction temperature on the yield of molecular hydrogen was revealed. The mechanisms of heterogeneous radiolysis of water involving the uranyl silicate and silicate samples under study were suggested.
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页码：1939 / 1943
页数：4
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