Complexation of Titanium Alkoxides with Cis-2-butene-1,4-diol and Hydrolysis of Their Products

被引：0
|
作者：
Asgar Kayan
机构：
[1] Kocaeli University,Department of Chemistry
来源：
Journal of Inorganic and Organometallic Polymers | 2003年 / 13卷
关键词：
Sol-gel; titanium alkoxides; -2-butene-1,4-diol; hydrolysis of metal alkoxides;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Reaction of Ti(OEt)4 and Ti(OBun)4 with cis-2-butene-1,4-diol (B.diol-2H) in 1:1 molar ratio was studied at room temperature using the sol-gel process. 13C{1H}- and 1H-NMR data showed that all the B.diol-2H completely reacted with both titanium alkoxides. Each of the products was hydrolyzed by water. The new hydrolyzed products were characterized by 13C- and 1H-NMR spectroscopy and Karl–Fischer Titration. Thermogravimetric and differential thermal analyses (TGA-DTA) of the hydrolyzed-products were also studied.
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页码：29 / 39
页数：10
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