Synthesis, spectroscopic characterization and crystal structure of mixed ligand Ni(II) complex of N-4-diethylaminosalicylidine-N′-4-nitrobenzoyl hydrazone and 4-picoline

被引:0
|
作者
Raj B. N. Bessy
Kurup M. R. Prathapachandra
E. Suresh
机构
[1] Cochin University of Science and Technology,Department of Applied Chemistry
[2] Central Salt and Marine Chemicals Research Institute,Analytical Science Division
来源
Structural Chemistry | 2006年 / 17卷
关键词
Ni(II) complex; Crystal structure; IR spectrum; UV-vis spectrum;
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摘要
A novel mixed ligand nickel complex [NiLB] [H2L-N-4-diethylaminosalicylidine-N′-4-nitrobenzoyl hydrazone and B-4-picoline] has been synthesized and characterized by elemental analysis, IR spectrum, UV-Vis spectrum and structure has been confirmed by single crystal X-ray structure analysis. The crystal structure reveals that the complex adopts distorted square planar structure with ONO donor atoms of primary ligand and N donor atom of the secondary ligand 4-picoline.
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页码:201 / 208
页数:7
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