Alkylation of tertiary arsines with methylene bromide and subsequent anion exchange

被引：0
|
作者：
R. D. Gigauri
L. G. Arabuli
R. I. Gigauri
N. I. Gurgenidze
M. A. Indzhiya
机构：
[1] Dzhavakhishvili Tbilisi State University,
来源：
Russian Journal of General Chemistry | 2006年 / 76卷
关键词：
Perchlorate; General Chemistry; Arsine; Alkyl Halide; Bromomethyl;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Tertiary arsines react with methylene bromide to give (bromomethyl)trialkyl(aryl)arsonium bromides. Treatment of the latter with magnesium perchlorate in aqueous ethanol solutions leads to anion exchange forming the corresponding tertiary arsonium perchlorates in nearly quantitative yields.
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页码：1576 / 1580
页数：4
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