Polymerization of methyl methacrylate using the NiX2(PPh3)2/Zn catalytic system

被引：0
|
作者：
I. S. Il’ichev
N. B. Valetova
M. V. Moskalev
D. F. Grishin
机构：
[1] Lobachevsky State University of Nizhni Novgorod,Research Institute for Chemistry
来源：
Kinetics and Catalysis | 2008年 / 49卷
关键词：
PMMA; Atom Transfer Radical Polymerization; Atom Transfer Radical Polymerization; Methyl Methacrylate; Nickel Complex;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The NiBr2(PPh3)2/Zn catalytic system in combination with the PhI initiator ensures methyl methacrylate polymerization in a wide temperature range. The polymer yield is determined by the ligand environment of the nickel atom, the reaction temperature, and the ratio of the components of the catalytic system. An analysis of the macrokinetic relationships and of the molecular-weight characteristics of the products indicates that polymerization occurs in a controlled regime.
引用
收藏
页码：531 / 536
页数：5
相关论文
共 50 条
  • [1] Polymerization of methyl methacrylate using the NiX2(PPh3)2/Zn catalytic system
    Il'ichev, I. S.
    Valetova, N. B.
    Moskalev, M. V.
    Grishin, D. F.
    KINETICS AND CATALYSIS, 2008, 49 (04) : 531 - 536
  • [2] Use of the NiBr2(PPh3)2/Zn catalytic system for homo- and copolymerization of styrene and methyl methacrylate
    Grishin, D. F.
    Il'ichev, I. S.
    Valetova, N. B.
    POLYMER SCIENCE SERIES B, 2009, 51 (3-4) : 89 - 95
  • [3] Use of the NiBr2(PPh3)2/Zn catalytic system for homo- and copolymerization of styrene and methyl methacrylate
    D. F. Grishin
    I. S. Il’ichev
    N. B. Valetova
    Polymer Science Series B, 2009, 51 : 89 - 95
  • [4] Catalytic effectiveness of azobisisobutyronitrile/[SiMes)Ru(PPH3)(Ind)Cl2 initiating system in the polymerization of methyl methacrylate and other vinylic monomers
    Al-Majid, Abdullah Mohammad
    Saeed, Waseem Sharaf
    Al-Odayni, Abdel-Basit Mohammed
    Alghamdi, Abdulaziz Ali
    Aouak, Taieb
    Nahra, Fady
    Nolan, Steven
    ARABIAN JOURNAL OF CHEMISTRY, 2018, 11 (07) : 1017 - 1031
  • [5] Amine additives for fast living radical polymerization of methyl methacrylate with RuCl2(PPh3)3
    Hamasaki, S
    Kamigaito, M
    Sawamoto, M
    MACROMOLECULES, 2002, 35 (08) : 2934 - 2940
  • [6] Living radical polymerization in water and alcohols:: Suspension polymerization of methyl methacrylate with RuCl2(PPh3)3 complex
    Nishikawa, T
    Kamigaito, M
    Sawamoto, M
    MACROMOLECULES, 1999, 32 (07) : 2204 - 2209
  • [7] Amino alcohol additives for the fast living radical polymerization of methyl methacrylate with RuCl2(PPh3)3
    Ando, T
    Sawauchi, C
    Ouchi, M
    Kamigaito, M
    Sawamoto, M
    JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2003, 41 (22) : 3597 - 3605
  • [8] ICAR ATRP of Styrene and Methyl Methacrylate with Ru(Cp*)Cl(PPh3)2
    Plichta, Andrzej
    Li, Wenwen
    Matyjaszewski, Krzysztof
    MACROMOLECULES, 2009, 42 (07) : 2330 - 2332
  • [9] RuH2(PPh3)4:: An active catalyst for living radical polymerization of methyl methacrylate at or above room temperature
    Takahashi, H
    Ando, T
    Kamigaito, M
    Sawamoto, M
    MACROMOLECULES, 1999, 32 (20) : 6461 - 6465
  • [10] Catalytic hydroethoxycarbonylation of octene-1 in the presence of the system PdCl2(PPh3)2–PPh3–AlCl3
    Kh. A. Suerbaev
    N. Zh. Khudaibergenov
    A. K. Kurmansitova
    Russian Journal of General Chemistry, 2016, 86 : 2124 - 2125
12345