Study of the interaction of imidazolidine-2-thione with molecular iodine

被引：0
|
作者：
M. S. Chernov’yants
T. S. Kolesnikova
K. Yu. Suponitsky
机构：
[1] Southern Federal University,Department of Chemistry
[2] Russian Academy of Sciences,A. N. Nesmeyanov Institute of Organoelement Compounds
来源：
Russian Chemical Bulletin | 2016年 / 65卷
关键词：
imidazolidine-2-thione; molecular adduct (C; H; N; S); •3I; UV spectroscopy; Raman spectroscopy; X-ray diffraction;
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学科分类号：
摘要：
The crystal and molecular structure of the reaction product of imidazolidine-2-thione and molecular iodine of the composition (C3H6N2S)2•3I2 was established by X-ray diffraction. The crystal structure is composed of strongly connected five-component associates consisting of three I2 molecules and two heterocyclic molecules. Quantum chemical calculations followed by the topological analysis of the electron density function provided an estimate of the strongest intermolecular interactions in the crystal structure of the molecular adduct.
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页码：811 / 815
页数：4
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