Synthesis and the crystal structure of the triosmium cluster with the μ-dehydrobenzene ligand, Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}

被引：0
|
作者：
A. A. Koridze
S. A. Kuklin
P. V. Petrovskii
F. M. Dolgushin
M. G. Ezernitskaya
机构：
[1] A. N. Nesmeyanov Institute of Organoelement Compounds,Russian Academy of Sciences
来源：
Russian Chemical Bulletin | 2002年 / 51卷
关键词：
triosmium clusters; dehydrobenzene complexes; hydrides; carbonylphosphines; protonation; -metallation; X-ray diffraction analysis;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph} complex, which was isolated from the products of thermolysis of Os3(CO)10(μ-dppm) (dppm is Ph2PCH2PPh2) in toluene, was characterized by X-ray diffraction analysis. Protonation of the resulting complex with trifluoroacetic acid afforded the cationic complex [Os3(μ-H)3(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}]+.
引用
收藏
页码：350 / 353
页数：3
相关论文
共 50 条
  • [1] Synthesis and the crystal structure of the triosmium cluster with the μ-dehydrobenzene ligand, Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}
    Koridze, AA
    Kuklin, SA
    Petrovskii, PV
    Dolgushin, FM
    Ezernitskaya, MG
    [J]. RUSSIAN CHEMICAL BULLETIN, 2002, 51 (02) : 350 - 353
  • [2] Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium cluster ”Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}”
    A. A. Koridze
    S. A. Kuklin
    N. A. Shtelzer
    P. V. Petrovskii
    F. M. Dolgushin
    M. G. Ezernitskaya
    [J]. Russian Chemical Bulletin, 2008, 57 : 2194 - 2197
  • [3] Synthesis and structures of complexes Os3(μ-H)2(CO)7(μ-RC5H3N){μ3-Ph2PCH2P(C6H4)Ph} (R = H, Me) with ortho-metalated pyridine ligands. The revised structure of the triosmium cluster "Os3(μ-H)2(CO)7(μ-C6H4){μ3-Ph2PCH2P(C6H4)Ph}"
    Koridze, A. A.
    Kuklin, S. A.
    Shtelzer, N. A.
    Petrovskii, P. V.
    Dolgushin, F. M.
    Ezernitskaya, M. G.
    [J]. RUSSIAN CHEMICAL BULLETIN, 2008, 57 (10) : 2194 - 2197
  • [4] Reactivity of [(μ-H)Os3(CO)8 {Ph2PCH2P(Ph)C6H4}] with organic heterothiols;: X-ray structures of [H(μ-H)Os3(CO)8(η2-pyS){Ph2PCH2P(Ph)C6H4}] and [Os3(CO)8(μ-η2-pyS){Ph2PCH2P(Ph)C6H4}]
    Kabir, SE
    Malik, KMA
    Molla, E
    Mottalib, MA
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2000, 616 (1-2) : 157 - 164
  • [5] Reactivity of the unsaturated triosmium cluster [Os3(CO)8{Ph2PCH2P(Ph)C6H4}(μ-H)] with thiols
    Abedin, SMT
    Azam, KA
    Hursthouse, MB
    Kabir, SE
    Malik, KMA
    Mottalib, MA
    Rosenberg, E
    [J]. JOURNAL OF CLUSTER SCIENCE, 2001, 12 (01) : 5 - 22
  • [6] Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS-SnPh3(pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand
    Joy, Md Tuhinur R.
    Ghosh, Shishir
    Kabir, Shariff E.
    [J]. JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2021, 51 (02) : 257 - 264
  • [7] Reactions of [Os3(CO)10(μ-H)2] and [Os3(CO)8{µ3-Ph2PCH2P(Ph)C6H4}(μ-H)] with pymS‒SnPh3 (pymS = pyrimidine-2-thiolate): Synthesis and Structure of Triosmium Clusters Containing pymS Ligand
    Md Tuhinur R. Joy
    Shishir Ghosh
    Shariff E. Kabir
    [J]. Journal of Chemical Crystallography, 2021, 51 : 257 - 264
  • [8] A comparative study of the reactivity of unsaturated triosmium clusters [Os3(CO)8{μ3-Ph2PCH2P(Ph)C6H4}(μ-H)] and [Os3(CO)9{μ3-η2-C7H3(2-Me)NS}-(μ-H)] with tBuNC
    Raha, Arun K.
    Ghosh, Shishir
    Karim, Md. Manzurul
    Tocher, Derek A.
    Begum, Noorjahan
    Sharmin, Ayesha
    Rosenberg, Edward
    Kabir, Shariff E.
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2008, 693 (24) : 3613 - 3621
  • [9] REACTION OF THE UNSATURATED TRIOSMIUM CLUSTERS [OS3H(CO)8-(PH2PCH2P(PH)C6H4)] AND [OS3H(CO)8(PH2PC(=CH2)P(PH)-C6H4)] WITH PHOSPHINES AND PHOSPHITES - CRYSTAL-STRUCTURES OF [OS3H(CO)8(PH2PCH2P(PH)C6H4)(PPR(I)3)], [OS3(CO)8(PH2PCH2-PPH2)(P(OME)3)2], AND [OS3(CO)8(PH2PCH2PPH2)(PPH3)2]
    BROWN, MP
    DOLBY, PA
    HARDING, MM
    MATHEWS, AJ
    SMITH, AK
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (11): : 1671 - 1679
  • [10] REACTION OF OS3H2(CO)9(C6H4) WITH DIPHENYLACETYLENE - THE FORMATION AND STRUCTURAL CHARACTERIZATION OF OS3(CO)7(C6H4)[PHCC(H)PH]2
    CHEN, H
    JOHNSON, BFG
    LEWIS, J
    RAITHBY, PR
    [J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1989, 376 (01) : C7 - C10
12345