Destruction of oxytetracycline using a microwave-assisted fused TiO2 photocatalytic oxidation system

被引:0
|
作者
Jaegu Park
Young-Kwon Park
Sang-Chul Jung
机构
[1] Sunchon National University,Department of Environmental Engineering
[2] University of Seoul,School of Environmental Engineering
来源
关键词
TiO; Oxytetracycline; Microwave; Electrodeless Lamp; Active Species;
D O I
暂无
中图分类号
学科分类号
摘要
We developed a novel and efficient degradation process for oxytetracycline (OTC), an antibiotic that remains in the aquatic environment and affects humans and animals. OTC was decomposed by applying a fusion TiO2 photocatalytic oxidation process adding microwaves, and various unit technologies and their fusion effects were investigated. As the microwave power increased, the decomposition efficiency increased, and the highest decomposition rate was shown in the neutral pH reaction solution. The decomposition rate was greatly increased by the addition of hydrogen peroxide, and it showed a synergistic effect that the decomposition efficiency was doubled by fusion with other processes. Eleven intermediate products of OCT decomposition were detected by liquid chromatography0mass spectrometry; CO2, H2O, NH4+, and NO4− by active oxidizing species, such as OH radicals generated by the microwave-assisted fused TiO2 photocatalytic oxidation process were mineralized.
引用
收藏
页码:3369 / 3376
页数:7
相关论文
共 50 条
  • [41] Microwave-Assisted Fabrication of Nanoparticulate TiO2 Microspheres for Synergistic Photocatalytic Removal of Cr(VI) and Methyl Orange
    Yang, Yong
    Wang, Guozhong
    Deng, Quan
    Ng, Dickon H. L.
    Zhao, Huijun
    ACS APPLIED MATERIALS & INTERFACES, 2014, 6 (04) : 3008 - 3015
  • [42] A Green and facile microwave-assisted synthesis of TiO2/graphene nanocomposite and their photocatalytic activity for methylene blue degradation
    Yang, Yuhao
    Liu, Enzhou
    Fan, Jun
    Hu, Xiaoyun
    Hou, Wenqian
    Wu, Feng
    Ma, Yongning
    RUSSIAN JOURNAL OF PHYSICAL CHEMISTRY A, 2014, 88 (03) : 478 - 483
  • [43] Effect of microwave field on preparation of TiO2 and photocatalytic oxidation of acetaldehyde
    Ding, ZX
    Wang, XX
    Fu, XZ
    Li, DZ
    CHINESE JOURNAL OF INORGANIC CHEMISTRY, 2005, 21 (08) : 1175 - 1180
  • [44] Photocatalytic destruction of phenol by TiO2 powders
    Kartal, ÖE
    Erol, M
    Oguz, H
    CHEMICAL ENGINEERING & TECHNOLOGY, 2001, 24 (06) : 645 - 649
  • [45] Microwave-assisted synthesis of Pt-WC/TiO2 in ionic liquid and its application for methanol oxidation
    Lang, Xiaoling
    Shi, Meiqin
    Chu, Youqun
    Liu, Weiming
    Chen, Zhaoyang
    Ma, Chunan
    JOURNAL OF SOLID STATE ELECTROCHEMISTRY, 2013, 17 (09) : 2401 - 2408
  • [46] Microwave-assisted synthesis of Pt-WC/TiO2 in ionic liquid and its application for methanol oxidation
    Xiaoling Lang
    Meiqin Shi
    Youqun Chu
    Weiming Liu
    Zhaoyang Chen
    Chunan Ma
    Journal of Solid State Electrochemistry, 2013, 17 : 2401 - 2408
  • [47] Electrochemically Assisted Photocatalytic Oxidation of Methanol on TiO2 Nanotube Arrays
    R.Mohammadpour
    A.Iraji zad
    N.Taghavinia
    M.Rahman
    M.M.Ahadian
    JournalofMaterialsScience&Technology, 2010, 26 (06) : 535 - 541
  • [48] Electrochemically Assisted Photocatalytic Oxidation of Methanol on TiO2 Nanotube Arrays
    Mohammadpour, R.
    Zad, A. Iraji
    Taghavinia, N.
    Rahman, M.
    Ahadian, M. M.
    JOURNAL OF MATERIALS SCIENCE & TECHNOLOGY, 2010, 26 (06) : 535 - 541
  • [49] Fenton-like oxidation of an azo dye using mesoporous Fe/TiO2 catalysts prepared by a microwave-assisted hydrothermal process
    Nesic, Jelena
    Manojlovic, Dragan D.
    Jovic, Milica
    Dojcinovic, Biljana P.
    Vulic, Predrag J.
    Krstic, Jugoslav
    Roglic, Goran M.
    JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2014, 79 (08) : 977 - 991
  • [50] Microwave-assisted synthesis of rod-like CuO/TiO2 for high-efficiency photocatalytic hydrogen evolution
    Yu, Yi-Hsien
    Chen, Ying-Pin
    Cheng, Zhengdong
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (46) : 15994 - 16000