Electrocatalytic evolution of hydrogen on amorphous Fe-Nb-B-Rare-Earth-Metal electrodes from alkaline solutions

被引：0
|
作者：
L. M. Boichyshyn
O. M. Hertsyk
M. A. Kovbus
T. G. Pereverzeva
B. Ya. Kotur
机构：
[1] Ivan Franko National University of Lviv,
来源：
Russian Journal of Applied Chemistry | 2014年 / 87卷
关键词：
Amorphous Alloy; Hydrogen Evolution; Cyclic Polarization; Amorphous Metallic Alloy; Free Potential;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Cathodic processes for electrochemical generation of hydrogen in aqueous KOH solutions in the presence of active electrodes made of Fe-Nb-B-based amorphous metallic alloys alloyed with rare-earth metals (Y, Gd, Dy) were studied. All the amorphous alloys exhibit a catalytic effect in the electrochemical evolution of hydrogen from 5 M aqueous KOH solutions. The electrocatalytic system with Fe82Nb2B14Gd2 and Fe82Nb2B14Dy2 electrodes exhibiting a prolonged autocatalytic effect can be recommended for practical application.
引用
收藏
页码：61 / 68
页数：7
相关论文
共 38 条
  • [1] Electrocatalytic evolution of hydrogen on amorphous Fe-Nb-B-Rare-Earth-Metal electrodes from alkaline solutions
    Boichyshyn, L. M.
    Hertsyk, O. M.
    Kovbus, M. A.
    Pereverzeva, T. G.
    Kotur, B. Ya.
    [J]. RUSSIAN JOURNAL OF APPLIED CHEMISTRY, 2014, 87 (01) : 61 - 68
  • [2] Electrocatalytic evolution of hydrogen on amorphous Fe-Nb-B-rare-earth- metal electrodes from alkaline solutions
    [J]. 1600, Izdatel'stvo Nauka (87):
  • [3] Electrocatalytic properties of Fe-R (R = rare earth metal) crystalline alloys as hydrogen electrodes in alkaline water electrolysis
    Rosalbino, F
    Macciò, D
    Angelini, E
    Saccone, A
    Delfino, S
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2005, 403 (1-2) : 275 - 282
  • [4] Electrocatalytic properties of Fe-R (R = rare earth metal) crystalline alloys as hydrogen electrodes in alkaline water electrolysis
    Rosalbino, F.
    Macciò, D.
    Angelini, E.
    Saccone, A.
    Delfino, S.
    [J]. Journal of Alloys and Compounds, 2005, 403 (1-2): : 275 - 282
  • [5] Electrocatalytic activity of metal-loaded reticulated vitreous carbon electrodes for hydrogen evolution from flowing alkaline solutions
    Saleh, Mahmoud M.
    El-Ankily, Maher H.
    El-Deab, Mohamed S.
    El-Anadouli, B. E.
    [J]. BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 2006, 79 (11) : 1711 - 1718
  • [6] Electrocatalytic activity of nickel black electrodes for the hydrogen evolution reaction in alkaline solutions
    [J]. 1600, (21):
  • [7] Platinum-rare earth electrodes for hydrogen evolution in alkaline water electrolysis
    Santos, D. M. F.
    Sequeira, C. A. C.
    Maccio, D.
    Saccone, A.
    Figueiredo, J. L.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (08) : 3137 - 3145
  • [8] ELECTROCATALYTIC ACTIVITY OF NICKEL BLACK ELECTRODES FOR THE HYDROGEN EVOLUTION REACTION IN ALKALINE-SOLUTIONS
    CHIALVO, AC
    DECHIALVO, MRG
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 1991, 21 (05) : 440 - 445
  • [9] ELECTROCATALYTIC PROPERTIES OF AMORPHOUS NICKEL BORIDE ELECTRODES FOR HYDROGEN EVOLUTION REACTION IN ALKALINE-SOLUTION
    LOS, P
    LASIA, A
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1992, 333 (1-2) : 115 - 125
  • [10] Electrocatalytic activity of Ni/C electrodes prepared by metal vapor synthesis for hydrogen evolution in alkaline solution
    Wu, SH
    Zhu, CY
    Huang, WP
    [J]. CHINESE CHEMICAL LETTERS, 1997, 8 (05) : 435 - 436
1234