Investigation of X-ray natural circular dichroism in a CsCuCl3 single crystal: Theory and experiment

被引：0
|
作者：
A. Rogalev
J. Goulon
F. Wilhelm
K. A. Kozlovskaya
E. N. Ovchinnikova
L. V. Soboleva
A. F. Konstantinova
V. E. Dmitrienko
机构：
[1] European Synchrotron Radiation Facility,Shubnikov Institute of Crystallography
[2] Moscow State University,undefined
[3] Russian Academy of Sciences,undefined
来源：
Crystallography Reports | 2008年 / 53卷
关键词：
61.10.-i; 61.14.Dc;
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学科分类号：
摘要：
X-ray natural circular dichroism in the near-Cu K edge in a CsCuCl3 single crystal, caused by dipole-quadrupole (E1E2) transitions between electronic states of different parity, has been experimentally and theoretically investigated. Numerical simulation of the experimental X-ray absorption spectrum and circular dichroism has been performed. It is established that a circular dichroism signal is observed in the pre-edge spectral region; therefore, it is mainly due to the localized electronic p-d states.
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页码：384 / 390
页数：6
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