Novel epitaxial growth of barium titanate thin films by electrodeposition

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作者
Jun Tamaki
Gregory K. L. Goh
Fred F. Lange
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[1] University of California Santa Barbara,Materials Department
[2] University of California Santa Barbara,Department of Chemistry, Faculty of Science and Engineering
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摘要
Electrodeposition was used to grow epitaxially BaTiO3 thin films on SrTiO3 single-crystal substrates with La0.7Sr0.3MnO3 (LSMO) conducting buffer layers. The epitaxial films appeared to consist of very small (ø10 nm) particles. The film completely covered the substrate when the reaction was performed at temperatures between 60 and 90 °C with LSMO potentials of –0.5 to –1.0 V against a Pt counter-electrode. It appeared that an electrophoretic force, acting on BaTiO3 nuclei within the solution, facilitated the deposition of the film.
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页码:2583 / 2586
页数:3
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