We present an analytical model of the charge density wave instability in graphene sheets within the intercalated graphite CaC6 compound. The instability yields the experimentally observed uniaxial charge stripes of periodically modulated electron density, coupled to the softest phonon mode of the superlattice consisting of the Ca atoms intercalated between graphene planes. The Fermi surface of the chemically doped graphene undergoes the novel type of instability driven by the mechanism that gains the condensation energy of the stripe state by the topological reconstruction of the Fermi surface. This mechanism appears to be entirely different from the one based on the Fermi surface nesting, which has been considered a paradigm in the present literature concerning the onset of charge density waves.
机构:
Univ Wollongong, ARC Ctr Excellence Electromat Sci, Intelligent Polymer Res Inst, Wollongong, NSW 2522, AustraliaUniv Wollongong, ARC Ctr Excellence Electromat Sci, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia
Li, Dan
Kaner, Richard B.
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Univ Calif Los Angeles, Dept Chem & Biochem, Los Angeles, CA 90095 USA
Univ Calif Los Angeles, Dept Mat Sci & Engn, Los Angeles, CA 90095 USA
Univ Calif Los Angeles, Calif Nanosyst Inst, Los Angeles, CA 90095 USAUniv Wollongong, ARC Ctr Excellence Electromat Sci, Intelligent Polymer Res Inst, Wollongong, NSW 2522, Australia