Thermal explosion in mechanoactivated 3Ni + Al mixtures

被引：0
|
作者：
M. A. Korchagin
V. Yu. Filimonov
E. V. Smirnov
N. Z. Lyakhov
机构：
[1] Russian Academy of Sciences,Institute of Solid State Chemistry and Mechanochemistry
[2] Siberian Branch,undefined
[3] Altai State Technical University,undefined
来源：
International Journal of Self-Propagating High-Temperature Synthesis | 2009年 / 18卷 / 2期
关键词：
SHS; thermal explosion; mechanical activation; 81.20 Ka; 81.20Wk; 64.70kd;
D O I：
10.3103/S1061386209020113
中图分类号：
学科分类号：
摘要：
Explored was thermal explosion in mechanoactivated 3Ni + Al mixtures. Mechanoactivation was found to result in an abnormal decrease in the effective activation energy E and ignition temperature Tign for thermal explosion. Analysis of reaction thermogram allowed us to find out the kinetic function. Mechanoactivation conditions for synthesis of Ni3Al in thermal explosion mode have been optimized. SHS reaction in 3Ni + Al mixtures mechanoactivated for 180 s was found to obey the first-order kinetics.
引用
收藏
页码：133 / 136
页数：3
相关论文
共 50 条
  • [1] Thermal Explosion in Mechanoactivated 3Ni
    Korchagin, M. A.
    Filimonov, V. Yu.
    Smirnov, E. V.
    Lyakhov, N. Z.
    [J]. INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS, 2009, 18 (02) : 133 - 136
  • [2] Simulation of thermal explosion in a pre-activated 3Ni + Al mixture
    O. V. Lapshin
    V. K. Smolyakov
    [J]. Combustion, Explosion, and Shock Waves, 2017, 53 : 548 - 553
  • [3] Macrokinetics of Solid-Phase Synthesis of an Activated 3Ni + Al Mixture in the Thermal Explosion Mode
    V. Yu. Filimonov
    M. A. Korchagin
    E. V. Smirnov
    N. Z. Lyakhov
    [J]. Combustion, Explosion, and Shock Waves, 2010, 46 : 449 - 456
  • [4] Anomalous decrease in the activation energy and initiation temperature of a thermal explosion in the mechanically activated composition 3Ni + Al
    V. Yu. Filimonov
    M. A. Korchagin
    V. V. Evstigneev
    N. Z. Lyakhov
    [J]. Doklady Physics, 2009, 54 : 277 - 280
  • [5] Effect of mechanical activation on thermal explosion in Ni-Al mixtures
    D. Yu. Kovalev
    N. A. Kochetov
    V. I. Ponomarev
    A. S. Mukasyan
    [J]. International Journal of Self-Propagating High-Temperature Synthesis, 2010, 19 (2) : 120 - 125
  • [6] MACROKINETICS OF REACTION AND THERMAL-EXPLOSION IN NI AND AL POWDER MIXTURES
    GASPARYAN, AG
    SHTEINBERG, AS
    [J]. COMBUSTION EXPLOSION AND SHOCK WAVES, 1988, 24 (03) : 324 - 330
  • [7] Effect of Mechanical Activation on Thermal Explosion in Ni-Al Mixtures
    Kovalev, D. Yu.
    Kochetov, N. A.
    Ponomarev, V. I.
    Mukasyana, A. S.
    [J]. INTERNATIONAL JOURNAL OF SELF-PROPAGATING HIGH-TEMPERATURE SYNTHESIS, 2010, 19 (02) : 120 - 125
  • [8] Thermokinetic characteristics of the final stage of the thermal shock of the 3Ni + Al + TiC powder mixture
    O. V. Lapshin
    E. N. Boyangin
    V. E. Ovcharenko
    [J]. Combustion, Explosion and Shock Waves, 2005, 41 : 64 - 70
  • [9] Thermal explosion of a mechanically activated 3Ni-Al mixture
    M. A. Korchagin
    V. Yu. Filimonov
    E. V. Smirnov
    N. Z. Lyakhov
    [J]. Combustion, Explosion, and Shock Waves, 2010, 46 : 41 - 46
  • [10] Thermal explosion of a mechanically activated 3Ni-Al mixture
    Korchagin, M. A.
    Filimonov, V. Yu.
    Smirnov, E. V.
    Lyakhov, N. Z.
    [J]. COMBUSTION EXPLOSION AND SHOCK WAVES, 2010, 46 (01) : 41 - 46
12345