On-line monitoring of the U(VI) concentration in 30 vol.% TBP/kerosene: an evaluation of real-time analysis in polyetheretherketone (PEEK) containers via Raman spectroscopy

被引:0
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作者
Xue Bai
Ding-Ming Li
Zhi-Yuan Chang
De-Jun Fan
Jin-Ping Liu
Hui Wang
机构
[1] China Institute of Atomic Energy,Department of Radiochemistry
关键词
On-line monitoring; U(VI) detection; PEEK; Raman spectroscopy; Internal standard; 30 vol.% TBP/kerosene;
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摘要
In order to evaluate the practicability of Raman spectroscopy for on-line U(VI) concentration monitoring in 30 vol.% TBP/kerosene within polyetheretherketone containers, laboratory scale experiments were performed and several influencing factors for real-time determination were investigated. A method of internal standard was employed for the first time. Software developed for real-time concentration data display can give the U(VI) concentration autonomously within several seconds. The study confirmed Raman spectroscopy as a promising methodology for on-line U(VI) concentration monitoring in organic phase.
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页码:643 / 652
页数:9
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