Transition metal catalysed diboration

被引：0
|
作者：
Todd B. Marder
Nicholas C. Norman
机构：
[1] The University of Durham,Department of Chemistry
[2] The University of Bristol,School of Chemistry
来源：
Topics in Catalysis | 1998年 / 5卷
关键词：
diboration; hydroboration; boron; platinum; rhodium; palladium; transition metal; homogeneous catalysis; boronate ester; arylboronate; vinylboronate; diboron; borylstannation; borylsilylation; silaboration; silicon; tin;
D O I：
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学科分类号：
摘要：
Homogeneous transition metal catalysed hydroboration reactions are discussed briefly, providing the background which led to the recent discovery of metal catalysed diborations [additions of the B–B bond in B2(OR)4 compounds] of alkynes, alkenes, 1,3-diynes, 1,3-dienes, and ά,βunsaturated ketones. Catalysed additions of B–Si and B–Sn bonds are also presented. Metal catalysed synthesis of organoboron compounds is a useful new synthetic method.
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页码：63 / 73
页数：10
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