Study on the oligomerization of cyclopentadiene and dicyclopentadiene to tricyclopentadiene through diels-alder reaction

被引：0

作者：

Zhongqiang Xiong

Zhentao Mi

Xiangwen Zhang

机构：

[1] Key Laboratory for Green Chemical Technology,

[2] School of Chemical Engineering and Technology,undefined

[3] Tianjin University,undefined

[4] Key Laboratory for Green Chemical Technology,undefined

[5] School of Chemical Engineering and Technology,undefined

[6] Tianjin University,undefined

[7] Key Laboratory for Green Chemical Technology,undefined

[8] School of Chemical Engineering and Technology,undefined

[9] Tianjin University,undefined

来源：

Reaction Kinetics and Catalysis Letters | 2005年 / 85卷

关键词：

Cyclopentadiene; dicyclopentadiene; tricyclopentadiene; oligomerization; Diels-Alder reaction;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The oligomerization of cyclopentadiene (CPD) and its dimer, dicyclopentadiene (DCPD), to tricyclopentadiene (TCPD) through Diels-Alder reaction at temperatures between 120 and 150°C was investigated. The results show that reaction temperature, pressure and solvent influence the product yield; at 150°C up to 50% yield of TCPD was obtained in the absence of solvents. The ratios of isomers A to B in the product can be adjusted by using different solvents. The kinetics indicate that the rate is more sensitive to the concentration of CPD than to that of DCPD.

引用

页码：89 / 97

页数：8

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