Structural motifs of mixed salts Ag2[Pd(NO2)4] · Ag1-xNaxNo2x > 0.3) and [Pd(NH3)4] [MA6] (M = Re, Os, Ir, Pt; A = Cl, Br)

被引：0
|
作者：
S. A. Gromilov
S. V. Korenev
S. P. Khranenko
V. I. Alekseev
机构：
[1] Russian Academy of Sciences,Institute of Inorganic Chemistry, Siberian Branch
来源：
Journal of Structural Chemistry | 1997年 / 38卷
关键词：
Unit Cell Parameter; Complex Anion; Mixed Salt; Palladium Atom; Heavy Fragment;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Mixed salts of noble metals with the general formula [Pd(NH3)4][MA6], where M = Re, Os, Ir, Pt;A = Cl,Br, and Ag2[Pd(NO2)4]-Ag1-xNaxNO2 (x> 0.3) have been synthesized and studied by X-ray diffractometry. It was found that the former are isostructural to each other and the latter are isostructural to Na2[Pd(NO2)4j-NaNO2. The structural motif of these compounds was established and metal-metal distances were estimated by the cation sublattice method In all cases, metal atoms form common cation sublattices with lattice parameters between 4.5 and 6.3 Å. An original approach to revealing common sublattices in crystal structures where the fragments differ considerably in weight is described.
引用
收藏
页码：96 / 102
页数：6
相关论文
共 50 条
  • [1] Structural motifs of mixed salts Ag-2[Pd(NO2)(4)]center dot Ag1-xNaxNO2 (x>0.3) and [Pd(NH3)(4)] [MA(6)] (M=Re, Os, Ir, Pt; A=Cl, Br)
    Gromilov, SA
    Korenev, SV
    Khranenko, SP
    Alekseev, VI
    JOURNAL OF STRUCTURAL CHEMISTRY, 1997, 38 (01) : 96 - 102
  • [2] CRYSTAL STRUCTURE OF [PT(NH3)2BR2][PT(NH3)2BR4], [(PD,PT)(NH3)2CL2][PD,PT)(NH3)2CL4] AND [PD(NH3)2CL2] [PD(NH3)2CL4]
    WALLEN, J
    BROSSET, C
    VANNERBERG, NG
    ARKIV FOR KEMI, 1962, 18 (06): : 541 - &
  • [3] Double Complex Salts [Co(NH3)5NO2][M(NO2)4] (M=Pt or Pd)
    Yusenko, Kirill
    Baidina, Iraida
    Korenev, Sergey
    ACTA CRYSTALLOGRAPHICA A-FOUNDATION AND ADVANCES, 2004, 60 : S276 - S276
  • [4] Syntheses and X-ray studies of the complexes [M(NH3)4][M′X6] (M = Pt, Pd; M′ = Re, Os; X = Cl, Br)
    A. I. Gubanov
    S. V. Korenev
    S. A. Gromilov
    I. A. Baidina
    A. B. Venediktov
    Journal of Structural Chemistry, 2000, 41 : 340 - 343
  • [5] Syntheses and X-ray studies of the complexes [M(NH3)4][M′X6] (M = Pt, Pd; M′ = Re, Os; X = Cl, Br)
    Gubanov, AI
    Korenev, SV
    Gromilov, SA
    Baidina, IA
    Venediktov, AB
    JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 41 (02) : 340 - 343
  • [6] Configurations of the [Pd(NO2)4]2- complex anion:: Crystal structure of Ag4A2 [M(NO2)4]3 (M = Pd, Pt; A= K, Rb)
    Gromilov, SA
    Baidina, IA
    Khranenko, SP
    Alekseev, VI
    Belyaev, AV
    JOURNAL OF STRUCTURAL CHEMISTRY, 2003, 44 (01) : 74 - 81
  • [7] Configurations of the [Pd(NO2)4]2- Complex Anion: Crystal Structure of Ag4A2[M(NO2)4]3 (M = Pd, Pt; A = K, Rb)
    S. A. Gromilov
    I. A. Baidina
    S. P. Khranenko
    V. I. Alekseev
    A. V. Belyaev
    Journal of Structural Chemistry, 2003, 44 : 74 - 81
  • [8] Double complex salts [Pd(NH3)4]3[Rh(NO2)6]2, [Pd(NH3)4]3[Rh(NO2)6]2•H2O as promising precursors to prepare Pd-Rh nanoalloys
    Rybinskaya, A. A.
    Plyusnin, P. E.
    Bykova, E. A.
    Gromilov, S. A.
    Shubin, Yu. V.
    Korenev, S. V.
    JOURNAL OF STRUCTURAL CHEMISTRY, 2012, 53 (03) : 527 - 533
  • [9] Double complex salts [Pd(NH3)4]3[Rh(NO2)6]2, [Pd(NH3)4]3[Rh(NO2)6]2·H2O as promising precursors to prepare Pd-Rh nanoalloys
    A. A. Rybinskaya
    P. E. Plyusnin
    E. A. Bykova
    S. A. Gromilov
    Yu. V. Shubin
    S. V. Korenev
    Journal of Structural Chemistry, 2012, 53 : 527 - 533
  • [10] Crystal structure of [Pd(NH3)4]3[Ir(NO2)6]2·H2O
    A. A. Rybinskaya
    E. A. Shusharina
    P. E. Plyusnin
    Yu. V. Shubin
    S. V. Korenev
    S. A. Gromilov
    Journal of Structural Chemistry, 2011, 52 : 816 - 819
12345