Effective adsorption of uranium(VI) from aqueous solution using ethylene-bridged mesoporous silica functionalized with ureido groups

被引:0
|
作者
Shidong Bao
Ye Li
Zhengfu Fei
Heng Mei
Yuzhi Zhou
Xiaoli Wang
Dongxue Liu
机构
[1] Wuhan University of Technology,School of Resources and Environmental Engineering
关键词
Uranium; Adsorption; Mesoporous silica; Ethylene-bridged; Ureido;
D O I
暂无
中图分类号
学科分类号
摘要
Ureido-functionalized ethylene-bridged mesoporous silica (UE-MS) was synthesized by co-condensation method for uranium(VI) uptake. The adsorbents were characterized by SEM, EDS, FTIR, BET and TGA. Through batch experiments, the effects of main factors on U(VI) sorption were investigated. The results indicated this adsorption was very fast with an equilibrium time of 30 min and negligibly affected by coexisting cations. At the optimum pH of 7, removal efficiency can exceed 99% with only 0.6 g/L of UE-MS dose. Furthermore, the adsorption process by UE-MS followed the quasi-second-order model and Freundlich model, and this process was spontaneous and endothermic.
引用
收藏
页码:385 / 394
页数:9
相关论文
共 50 条
  • [1] Effective adsorption of uranium(VI) from aqueous solution using ethylene-bridged mesoporous silica functionalized with ureido groups
    Bao, Shidong
    Li, Ye
    Fei, Zhengfu
    Mei, Heng
    Zhou, Yuzhi
    Wang, Xiaoli
    Liu, Dongxue
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2020, 324 (01) : 385 - 394
  • [2] Adsorption of uranium(VI) from aqueous solution using phosphonic acid-functionalized silica magnetic microspheres
    Zhou, Limin
    Zou, Hongbin
    Wang, Yun
    Liu, Zhirong
    Huang, Zhiwei
    Luo, Taian
    Adesina, Adesoji A.
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2016, 310 (03) : 1155 - 1163
  • [3] Adsorption of uranium(VI) from aqueous solution using phosphonic acid-functionalized silica magnetic microspheres
    Limin Zhou
    Hongbin Zou
    Yun Wang
    Zhirong Liu
    Zhiwei Huang
    Taian Luo
    Adesoji A. Adesina
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2016, 310 : 1155 - 1163
  • [4] Structure-adsorption properties of ethylene-bridged polysilsesquioxanes and polysiloxanes functionalized with different groups
    Barczak, M.
    Borowski, P.
    Dabrowski, A.
    [J]. COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2009, 347 (1-3) : 114 - 120
  • [5] Diethylenetriamine functionalized silica gel for adsorption of uranium from aqueous solution and seawater
    P. Amesh
    K. A. Venkatesan
    A. S. Suneesh
    Deepak K. Gupta
    T. R. Ravindran
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2021, 329 : 337 - 349
  • [6] Diethylenetriamine functionalized silica gel for adsorption of uranium from aqueous solution and seawater
    Amesh, P.
    Venkatesan, K. A.
    Suneesh, A. S.
    Gupta, Deepak K.
    Ravindran, T. R.
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2021, 329 (01) : 337 - 349
  • [7] Cr(VI) adsorption on functionalized amorphous and mesoporous silica from aqueous and non-aqueous media
    Perez-Quintanilla, Damian
    del Hierro, Isabel
    Fajardo, Mariano
    Sierra, Isabel
    [J]. MATERIALS RESEARCH BULLETIN, 2007, 42 (08) : 1518 - 1530
  • [8] Adsorption of uranium(VI) from aqueous solution by diethylenetriamine-functionalized magnetic chitosan
    Xu, Jinsheng
    Chen, Mansheng
    Zhang, Chunhua
    Yi, Zhengji
    [J]. JOURNAL OF RADIOANALYTICAL AND NUCLEAR CHEMISTRY, 2013, 298 (02) : 1375 - 1383
  • [9] Adsorption of uranium(VI) from aqueous solution by diethylenetriamine-functionalized magnetic chitosan
    Jinsheng Xu
    Mansheng Chen
    Chunhua Zhang
    Zhengji Yi
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2013, 298 : 1375 - 1383
  • [10] Adsorption of uranium (VI) from aqueous solution by tetraphenylimidodiphosphinate
    Juan Tan
    Yanfei Wang
    Na Liu
    Mouwu Liu
    [J]. Journal of Radioanalytical and Nuclear Chemistry, 2018, 315 : 119 - 126