Defluorination and adsorption of tetrafluoroethylene (TFE) on TiO2(110) and Cr2O3(0001)

被引：0
|
作者：
Jessiel Siaron Gueriba
Nur Ellina Annisa Salehuddin
Wilson Agerico Diño
Kiminori Washika
Hiroshi Nakamura
Tatsumi Kawafuchi
机构：
[1] Osaka University,Department of Applied Physics
[2] De La Salle University,Department of Physics
[3] Osaka University,Institute of Laser Engineering
[4] Universiti Kebangsaan Malaysia,Department of Chemical Sciences, Faculty of Science and Technology
[5] Osaka University,Center for Atomic and Molecular Technologies
[6] Hirotec Co.,Laser Technology Laboratory
[7] Ltd,Research and Development Division, Technology Development Department
[8] Charmant Inc.,undefined
来源：
Scientific Reports | / 11卷
关键词：
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Here, we show that metal oxide surfaces catalyze the formation of intermediate defluorinated tetrafluoroethylene (TFE) radicals, resulting in enhanced binding on the corresponding metal oxide surfaces. We attribute the preferential adsorption and radical formation of TFE on Cr2O3(0001) relative to TiO2(110) to the low oxygen coordination of Cr surface atoms. This hints at a possible dependence of the TFE binding strength to the surface stoichiometry of metal-oxide surfaces.
引用
收藏
相关论文
共 50 条
  • [1] Defluorination and adsorption of tetrafluoroethylene (TFE) on TiO2(110) and Cr2O3(0001)
    Gueriba, Jessiel Siaron
    Salehuddin, Nur Ellina Annisa
    Dino, Wilson Agerico
    Washika, Kiminori
    Nakamura, Hiroshi
    Kawafuchi, Tatsumi
    [J]. SCIENTIFIC REPORTS, 2021, 11 (01)
  • [2] CO2 adsorption on Cr(110) and Cr2O3(0001)/Cr(110)
    Funk, S.
    Nurkic, T.
    Hokkanen, B.
    Burghaus, U.
    [J]. APPLIED SURFACE SCIENCE, 2007, 253 (17) : 7108 - 7114
  • [3] CO2 adsorption on Cr2O3(0001)/Cr(110)
    Funk, S.
    Hokkanen, B.
    Nurkic, T.
    Burghaus, U.
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2007, 233
  • [4] Adsorption and reaction of magnesium on Cr2O3(0001)/Cr(110)
    Bender, M
    Yakovkin, IN
    Freund, HJ
    [J]. SURFACE SCIENCE, 1996, 365 (02) : 394 - 402
  • [5] Adsorption and reaction of ethene on Cr2O3(0001)/Cr(110)
    Hemmerich, I
    Rohr, F
    Seiferth, O
    Dillmann, B
    Freund, HJ
    [J]. ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-INTERNATIONAL JOURNAL OF RESEARCH IN PHYSICAL CHEMISTRY & CHEMICAL PHYSICS, 1997, 202 : 31 - 43
  • [6] Adsorption of CO on Cr2O3(0001)
    Pykavy, M
    Staemmler, V
    Seiferth, O
    Freund, HJ
    [J]. SURFACE SCIENCE, 2001, 479 (1-3) : 11 - 25
  • [7] IR investigations of CO2 adsorption on chromia surfaces:: Cr2O3 (0001)/Cr(110) versus polycrystalline α-Cr2O3
    Seiferth, O
    Wolter, K
    Dillmann, B
    Klivenyi, G
    Freund, HJ
    Scarano, D
    Zecchina, A
    [J]. SURFACE SCIENCE, 1999, 421 (1-2) : 176 - 190
  • [8] Interaction and diffusion of potassium on Cr2O3(0001)/Cr(110)
    Zhao, W
    Kerner, G
    Asscher, M
    Wilde, XM
    Al-Shamery, K
    Freund, HJ
    Staemmler, V
    Wieszbowska, M
    [J]. PHYSICAL REVIEW B, 2000, 62 (11): : 7527 - 7534
  • [9] Structure and defects of epitaxial Cr2O3(0001) overlayers on Cr(110)
    Stierle, A
    Koll, T
    Zabel, H
    [J]. PHYSICAL REVIEW B, 1998, 58 (08): : 5062 - 5069
  • [10] Adsorption of methanol and methoxy on the α-Cr2O3(0001) surface
    Borck, Oyvind
    Schroder, Elsebeth
    [J]. JOURNAL OF PHYSICS-CONDENSED MATTER, 2006, 18 (48) : 10751 - 10763
12345