Free radical copolymerization of methyl methacrylate and N-2-methyl-4-nitro-phenylmaleimide: Improvement in the Tg of PMMA

被引：0
|
作者：
Fariborz Atabaki
Amir Abdolmaleki
Abdolvahid Barati
机构：
[1] Malek-ashtar University of Technology,Department of Chemistry
[2] Isfahan University of Technology,Organic Polymer Chemistry Research Laboratory, Department of Chemistry
[3] Isfahan University of Technology,Nanotechnology and Advanced Materials Institute
来源：
Colloid and Polymer Science | 2016年 / 294卷
关键词：
Copolymerization; Maleimide; Methyl methacrylate; Thermal stability; Glass transition temperature;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
In this investigation, a series of novel poly(methyl methacrylate-co-N-2-methyl-4-nitrophenylmaleimide) (PMMA-co-MI) copolymers possessing high glass transition temperatures (Tg) and high transparency was prepared through free radical polymerization. The resultant copolymers were characterized by spectroscopic techniques, elemental analysis, X-ray diffraction, and thermal methods. The PMMA-co-MI copolymers demonstrate higher thermal stability as compared to pristine PMMA. The Tg of copolymers is about 40 °C more than for PMMA. The copolymer composition has been determined by elemental analysis and 1H-NMR. The investigated copolymers show excellent solubility in wide range of organic solvents.
引用
收藏
页码：455 / 462
页数：7
相关论文
共 50 条
  • [1] Free radical copolymerization of methyl methacrylate and N-2-methyl-4-nitro-phenylmaleimide: Improvement in the Tg of PMMA
    Atabaki, Fariborz
    Abdolmaleki, Amir
    Barati, Abdolvahid
    COLLOID AND POLYMER SCIENCE, 2016, 294 (02) : 455 - 462
  • [2] Free radical copolymerization of 2-aminoethyl methacrylate with methyl methacrylate
    Copolymerisation radicalaire de methacrylates de 2-aminoethyle avec le methacrylate de methyle
    Camail, M., 1600, Pergamon Press Ltd, Oxford, United Kingdom (31):
  • [3] Kinetic Treatment for Copolymerization of Styrene or Methyl Methacrylate with N-phenylmaleimide
    单国荣
    翁志学
    黄志明
    潘祖仁
    Chinese Journal of Chemical Engineering, 2000, (01) : 5 - 9
  • [4] COPOLYMERIZATION OF METHYL-METHACRYLATE WITH N-PHENYLMALEIMIDE IN DIFFERENT SOLVENTS
    ELSABEE, MZ
    SABAA, MW
    NAGUIB, HF
    FURUHATA, K
    JOURNAL OF MACROMOLECULAR SCIENCE-CHEMISTRY, 1987, A24 (10): : 1207 - 1221
  • [5] Kinetic treatment for copolymerization of styrene or methyl methacrylate with N-phenylmaleimide
    Shan, Guorong
    Weng, Zhixue
    Huang, Zhiming
    Pan, Zuren
    2000, Chemical Industry Press, China (08):
  • [6] Kinetic treatment for copolymerization of styrene or methyl methacrylate with N-phenylmaleimide
    Shan, GR
    Weng, ZX
    Huang, ZM
    Pan, ZR
    CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2000, 8 (01) : 1 - 5
  • [7] Free-radical copolymerization of [(4-isopropyl phenyl) oxycarbonyl] methyl methacrylate with acrylonitrile and methyl methacrylate
    Soykan, C., 1600, John Wiley and Sons Inc. (88):
  • [8] Free-radical copolymerization of [(4-isopropyl phenyl) oxycarbonyl] methyl methacrylate and acrylonitrile and methyl methacrylate
    Soykan, C
    Erol, I
    JOURNAL OF APPLIED POLYMER SCIENCE, 2003, 88 (09) : 2331 - 2338
  • [9] Free radical copolymerization of methyl methacrylate and styrene with N-(4-carboxyphenyl)maleimide
    Oswal, Shantilal
    Bhandari, Vijay K.
    Bhamore, Priti
    Malek, Naved I.
    International Journal of Polymeric Materials and Polymeric Biomaterials, 2007, 56 (04) : 421 - 435
  • [10] Copolymerization of n-butyl acrylate with methyl methacrylate and PMMA macromonomers by conventional and atom transfer radical copolymerization
    Roos, Sebastian G.
    Muller, Axel H. E.
    Matyjaszewski, Krzysztof
    ACS Symposium Series, 2000, 768 : 361 - 371
12345