Two new cadmium(II) coordination polymers with bis(benzimidazole) ligands

被引：0
|
作者：
X.-B. Liu
Y.-Q. Zhao
W.-L. Liu
G.-H. Cui
机构：
[1] North China University of Science and Technology,College of Chemical Engineering
来源：
Journal of Structural Chemistry | 2017年 / 58卷
关键词：
bis(benzimidazole; cadmium(II) coordination polymer; crystal structure; fluorescence;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
Two new cadmium(II) coordination polymers, {[Cd(L1)(tbta)]·H2O}n (1) and [Cd(L2)(tbta)]n (2) (L1 = 1,4-bis(5,6-dimethylbenzimidazol-1-ylmethyl)benzene, H2tbta = tetrabromoterephthalic acid and L2 = 1,4-bis(2-methylbenzimidazol-1-ylmethyl)benzene) are obtained under hydrothermal conditions and structurally characterized by single crystal X-ray diffraction methods, IR spectroscopy, TGA and elemental analysis. The L1 and L2 ligands differ by subtle variation of substituents at semi-rigid bis(benzimidazole) bakcbones. Complex 1 features a 3D threefold interpenetrating dia array with a 4-connected 66 topology. Complex 2 displays a 2D {44.62} sql/Shubnikov tetragonal plane network. Complexes 1 and 2 possess high thermal stabilities and promising fluorescence behavior in the solid state.
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页码：750 / 757
页数：7
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