Nontransition metal–crown ether complexes as hydroperoxide decomposition catalysts

被引：0
|
作者：
N. M. Nurullina
N. N. Batyrshin
Kh. E. Kharlampidi
V. I. Anisimova
I. A. Suvorova
机构：
[1] Kazan National Research Technical University,
来源：
Kinetics and Catalysis | 2016年 / 57卷
关键词：
catalytic decomposition; -butyl hydroperoxide; dibenzo-18-crown-6; calcium; strontium; and barium chlorides;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The decomposition of tert-butyl hydroperoxide in a chlorobenzene medium in the presence of complexes of dibenzo-18-crown-6 with calcium, strontium, and barium chlorides has been studied. It has been found and kinetically proven that the decomposition of tert-butyl hydroperoxide is preceded by the formation of an intermediate hydroperoxide–catalyst complex. Kinetic and thermodynamic parameters of the complex formation have been determined.
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页码：434 / 438
页数：4
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