Ion-selective properties of 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L1) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L2). Crystal structure of complexes [CdI2(μ-L1)]2, [CdBr2 (μ-L1)]2 · C2H5OH, and [Cd(L2)2(H2O)2][Cd2I6]

被引：0

作者：

I.S. Ivanova

I.N. Polyakova

E.S. Krivorot’ko

E.N. Pyatova

V.E. Baulin

A.Yu. Tsivadze

机构：

[1] Russian Academy of Sciences,Kurnakov Institute of General and Inorganic Chemistry

[2] Russian Academy of Sciences,Frumkin Institute of Physical Chemistry and Electrochemistry

[3] Russian Academy of Sciences,Institute of Physiologically Active Substances

来源：

Russian Journal of Inorganic Chemistry | 2017年 / 62卷

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摘要：

Ion-selective properties of polymeric plasticized membranes of ion-selective electrodes based on 1,2-bis[2-(2-diphenylphosphorylmethylphenoxy)ethoxy]benzene (L1) and 1,2-bis[2-(2-diphenylphosphorylphenoxy)ethoxy]benzene (L2) toward certain bivalent metal cations has been studied. It has been shown that podand L2 can be used as a sensor component of polymeric plasticized membrane of ion-selective electrode for quantitative determination of Pb2+ ions in aqueous solutions. The structure of complexes [CdI2(μ-L1)]2, [Cd(μ-L1)Br2]2 · C2H5OH, and [Cd(L2)2(H2O)2][Cd2I6] has been studied by X-ray diffraction and IR spectroscopy.

引用

页码：1299 / 1307

页数：8

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